dc.citation.conferencePlace |
KO |
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dc.citation.conferencePlace |
대전 |
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dc.citation.title |
2012 한국 세라믹 학회 추계 연구발표회 |
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dc.contributor.author |
Kim, Guntae |
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dc.contributor.author |
Sengodan, Sivaprakash |
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dc.contributor.author |
Shin, Jeeyoung |
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dc.date.accessioned |
2023-12-20T01:39:42Z |
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dc.date.available |
2023-12-20T01:39:42Z |
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dc.date.created |
2013-07-17 |
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dc.date.issued |
2012-10-18 |
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dc.description.abstract |
Non-stoichiometric variation of oxygen content in La0.8Sr0.2 ScyMn1-yO3±δ (y = 0.2, 0.3, 0.4) were determined by means of coulometric titration as a function of oxygen partial pressure p(O2) and temperature. La0.8Sr0.2ScyMn1-yO3±δ oxides shows oxygen excess and oxygen deficient composition depending on p(O2). Random defect model was constructed based on the experimental oxygen non-stoichiometry. The non-stoichiometric variation of oxygen content of La0.8Sr0.2ScyMn1-yO3±δ can be explained by the defect equilibrium model. Thermodynamic quantities such as partial molar enthalpy and partial molar entropy were calculated using Gibbs-Hemholtz equation. Electrical conductivity measurements were performed as a function of oxygen partial pressure and temperature, which shows a typical p-type behavior. |
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dc.identifier.bibliographicCitation |
2012 한국 세라믹 학회 추계 연구발표회 |
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dc.identifier.uri |
https://scholarworks.unist.ac.kr/handle/201301/43240 |
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dc.language |
영어 |
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dc.publisher |
한국 세라믹 학회 |
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dc.title |
Oxygen non-stoichiometry, defect equilibrium and electrical properties of La0.8Sr0.2ScyMn1-yO3±δ (y = 0.2, 0.3, 0.4) |
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dc.type |
Conference Paper |
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dc.date.conferenceDate |
2012-10-18 |
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