dc.citation.conferencePlace |
KO |
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dc.citation.conferencePlace |
Daejeon |
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dc.citation.number |
1 |
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dc.citation.title |
2015년도 춘계 정기총회 및 연구논문발표 |
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dc.citation.volume |
40 |
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dc.contributor.author |
Yang, Changduk |
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dc.contributor.author |
Lee, Sangmyun |
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dc.contributor.author |
Lee, Jeonghoon |
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dc.contributor.author |
Han, Aareum |
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dc.contributor.author |
Yoo, Dohyuk |
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dc.contributor.author |
Oh, Joonhak |
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dc.date.accessioned |
2023-12-19T22:39:21Z |
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dc.date.available |
2023-12-19T22:39:21Z |
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dc.date.created |
2016-01-12 |
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dc.date.issued |
2015-04-08 |
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dc.description.abstract |
In this report, a practical variation of the Suzuki polymerization to generate semiconducting polymeric hybrids based on siloxane units, which proceeds under essentially non-basic conditions, is presented and optimized. This method can be used to generate solution-processable poly(diketopyrrolopyrrole-alt-benzothiadiazole) (PDPPBT-Si) polymer consisting of the hybrid siloxane substituents, which could not be made using conventional methods. PDPPBT-Si exhibits excellent ambipolar transistor performance with well-balanced hole and electron FET mobilities. The siloxane-containing DPP-thiophene polymer classes (PDPP3T-Si and PDPP4T-Si), synthesized via this method, exhibit high hole mobility of up to 1.29 cm2 V-1 s-1. This synthetic approach should provide access to a variety of novel siloxane-containing conjugated semiconductor classes via a selection of aryldihalides and aryldiboronic acids/esters. |
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dc.identifier.bibliographicCitation |
2015년도 춘계 정기총회 및 연구논문발표, v.40, no.1 |
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dc.identifier.uri |
https://scholarworks.unist.ac.kr/handle/201301/42208 |
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dc.identifier.url |
https://www.cheric.org/research/tech/proceedings/view.php?seq=119069&proceedingssearch=postech |
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dc.language |
영어 |
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dc.publisher |
한국고분자학회 |
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dc.title |
Base-Free Suzuki Polymerization with Fluoride-salt Mediated for Siloxane-Based Hybrid Semiconducting Polymers |
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dc.type |
Conference Paper |
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dc.date.conferenceDate |
2015-04-08 |
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