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Kim, Jin Young
Next Generation Energy Laboratory
Research Interests
  • Polymer solar cells, QD solar cells, organic-inorganic hybrid solar cells, perovskite solar cells, OLEDs, PeLEDs, organic FETs

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Pyrrolo[3,2-b]pyrrole-Based Copolymers as Donor Materials for Organic Photovoltaics

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dc.contributor.author Song, Suhee ko
dc.contributor.author Ko, Seo-Jin ko
dc.contributor.author Shin, Hyunmin ko
dc.contributor.author Jin, Youngeup ko
dc.contributor.author Kim, Il ko
dc.contributor.author Kim, Jin Young ko
dc.contributor.author Suh, Hongsuk ko
dc.date.available 2014-04-10T02:34:36Z -
dc.date.created 2014-01-06 ko
dc.date.issued 2013-11 -
dc.identifier.citation BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.34, no.11, pp.3399 - 3404 ko
dc.identifier.issn 1229-5949 ko
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/4003 -
dc.identifier.uri http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84889018037 ko
dc.description.abstract A new accepter unit, pyrrolo[3,2-b]pyrrole-2,5-dione, was prepared and utilized for the synthesis of the conjugated polymers containing electron donor-acceptor pair for OPVs. Pyrrolo[3,2-b]pyrrole-2,5-dione unit, regioisomer of the known pyrrolo[3,4-c]pyrrole-1,4-dione, is originated from the structure of stable synthetic pigment. The new conjugated polymers with 1,4-diphenylpyrrolo[3,2-b]pyrrole-2,5-dione, thiophene and carbazole were synthesized using Suzuki polymerization to generate P1 and P2. The solid films of P1 and P2 show absorption bands with maximum peaks at about 377, 554 and 374, 542 nm and the absorption onsets at 670 and 674 nm, corresponding to band gaps of 1.85 and 1.84 eV, respectively. To improve the hole mobility of the polymer with 1,4-bis(4-butylphenyl)-pyrrolo[3,2-b]-pyrrole-2,5-dione unit, which was previously reported by us, the butyl group at the 4-positions of the N-substituted phenyl group was substituted with hydrogen and methyl group. The field-effect hole mobility of P2 is 9.6 × 10-5 cm2/Vs. The device with P2:PC71BM (1:2) showed VOC value of 0.84 V, JSC value of 5.10 mA/cm2, and FF of 0.33, giving PCE of 1.42%. ko
dc.description.statementofresponsibility close -
dc.language ENG ko
dc.publisher KOREAN CHEMICAL SOC ko
dc.subject Absorption onset ko
dc.subject Donor materials ko
dc.subject Electron donor acceptors ko
dc.subject Organic photovoltaics ko
dc.subject Polymer-based solar cells ko
dc.subject Pyrrolo[3,2-b]pyrrole-2,5- dione ko
dc.subject Suzuki polymerization ko
dc.subject Synthetic pigments ko
dc.title Pyrrolo[3,2-b]pyrrole-Based Copolymers as Donor Materials for Organic Photovoltaics ko
dc.type ARTICLE ko
dc.identifier.scopusid 2-s2.0-84889018037 ko
dc.identifier.wosid 000327689400049 ko
dc.type.rims ART ko
dc.description.wostc 0 *
dc.description.scopustc 0 *
dc.date.tcdate 2014-10-18 *
dc.date.scptcdate 2014-07-12 *
dc.identifier.doi 10.5012/bkcs.2013.34.11.3399 ko
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