dc.citation.conferencePlace |
KO |
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dc.citation.title |
IUPAC-PSK40 (International Conference on Advanced Polymeric Materials) |
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dc.contributor.author |
Kim, Jimin |
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dc.contributor.author |
Bok, Taesoo |
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dc.contributor.author |
Jeena, M. T. |
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dc.contributor.author |
Park, Soojin |
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dc.contributor.author |
Ryu, Ja-Hyoung |
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dc.date.accessioned |
2023-12-19T20:08:15Z |
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dc.date.available |
2023-12-19T20:08:15Z |
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dc.date.created |
2016-12-29 |
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dc.date.issued |
2016-10-04 |
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dc.description.abstract |
Si has received attention as active material in anode due to its high theoretical charge capacity but the Si anode has big challenge result from the large volume expansion,>300% at lithiation. This expansion causes isolated, dead Si and rapidly fading the capacity of electrode. To alleviate this ephemeral ability we introduce boronic acid polymeric cross-linker for stable binding of Si. Boronic acids of cross-linker form stable chemical crosslink with hydroxyl groups of binder. By using polymeric cross-linker, cross-linker can make bond with binder in broader range than simple material. And we use ultrahigh molecular weight polymer binder of PAA-PVA random copolymer due to their high viscosity and abundant functional group. Acrylic acid of binder have good adhesion with Cu foil and Si particle. And Boronic acid of cross-linker and alcohol group of PAA-PVA binder form in situ chemical crosslink by heat treat. By using elastic and entangled polymer, cross-linked binder efficiently grasp expanded Si and prevent isolation of contracted Si. This crosslinking of boronic acid cross-linker and PAA-PVA binder will maintain electrode and improve lifetime and capacity of Li ion battery. |
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dc.identifier.bibliographicCitation |
IUPAC-PSK40 (International Conference on Advanced Polymeric Materials) |
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dc.identifier.uri |
https://scholarworks.unist.ac.kr/handle/201301/39919 |
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dc.identifier.url |
http://www.dbpia.co.kr/Journal/ArticleDetail/NODE07048855 |
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dc.language |
영어 |
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dc.publisher |
IUPAC-한국고분자학회 |
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dc.title |
Crosslinked Ultra High Molecular Polymeric Binder using Boronic Acid for Si Anode in Li Battery |
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dc.type |
Conference Paper |
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dc.date.conferenceDate |
2016-10-04 |
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