dc.citation.conferencePlace |
US |
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dc.citation.title |
Gordon Research Conferences on Batteries |
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dc.contributor.author |
Kim, Young-Soo |
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dc.contributor.author |
Cho, Yoon-Gyo |
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dc.contributor.author |
Odkhuu, Dorj |
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dc.contributor.author |
Song, Hyun-Kon |
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dc.contributor.author |
Park, Noejung |
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dc.date.accessioned |
2023-12-20T00:09:15Z |
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dc.date.available |
2023-12-20T00:09:15Z |
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dc.date.created |
2014-07-22 |
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dc.date.issued |
2014-03-09 |
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dc.description.abstract |
Electrolytes are characterized by their ionic conductivity (sigma(i)). It is desirable that overall si results from the dominant contribution of the ions of interest (e. g. Li+ in lithium ion batteries or LIB). However, high values of cationic transference number (t(+)) achieved by solid or gel electrolytes have resulted in low sigma(i) leading to inferior cell performances. Here we present an organogel polymer electrolyte characterized by a high liquid-electrolyte-level sigma(i) (similar to 10(1) mS cm(-1)) with high t(+) of Li+ (>0.8) for LIB. A conventional liquid electrolyte in presence of a cyano resin was physically and irreversibly gelated at 60 degrees C without any initiators and crosslinkers, showing the behavior of lower critical solution temperature. During gelation, sigma(i) of the electrolyte followed a typical Arrhenius-type temperature dependency, even if its viscosity increased dramatically with temperature. Based on the Li+-driven ion conduction, LIB using the organogel electrolyte delivered significantly enhanced cyclability and thermal stability. |
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dc.identifier.bibliographicCitation |
Gordon Research Conferences on Batteries |
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dc.identifier.uri |
https://scholarworks.unist.ac.kr/handle/201301/36963 |
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dc.language |
영어 |
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dc.publisher |
Gordon Research Conferences on Batteries |
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dc.title |
A physical organogel electrolyte:characterized by in situ thermo-irreversible gelation and single-ion-predominent conduction |
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dc.type |
Conference Paper |
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dc.date.conferenceDate |
2014-03-09 |
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