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Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)
  • Crystal Engineering
  • Supramolecular coordination chemistry

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Crystal-to-Crystal Transformations of a Series of Isostructural Metal-Organic Frameworks with Different Sizes of Ligated Solvent Molecules

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dc.contributor.author Oh, Minhak ko
dc.contributor.author Rajput, Lalit ko
dc.contributor.author Kim, Dongwook ko
dc.contributor.author Moon, Dohyun ko
dc.contributor.author Lah, Myoung Soo ko
dc.date.available 2014-04-10T01:52:30Z -
dc.date.created 2013-07-01 ko
dc.date.issued 2013-04 -
dc.identifier.citation INORGANIC CHEMISTRY, v.52, no.7, pp.3891 - 3899 ko
dc.identifier.issn 0020-1669 ko
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/3379 -
dc.identifier.uri http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84875764429 ko
dc.description.abstract Isostructural 3D metal-organic frameworks (MOFs) [Zn-2(BTC)(NO3)S-3] [where BTC = 1,3,5-benzenetricarboxylate; S = EtOH (1), DMF (2), DMA (3), or DEF (4)] of a 3-connected srs net topology have been prepared in the presence of serine as a template. The MOFs show different framework stabilities depending on the sizes of the ligated solvent molecules and undergo a crystal-to-crystal transformation at ambient conditions into a ID chain structure either directly or via different types of intermediates depending on the ligated solvent molecules and the sample handling conditions. A single crystal of the MOF with the ligated DMF molecules, [Zn-2(BTC)(NO3)(DMF)(3)] (2), is stable in Mg-II- and Co-II-DMF solutions; however, it transforms into a sing,le particle-like microcrystalline aggregate of Cu-HKUST-1 in a Cu-II-DMF solution. ko
dc.description.statementofresponsibility close -
dc.language ENG ko
dc.publisher AMER CHEMICAL SOC ko
dc.subject INDUCED SINGLE-CRYSTAL ko
dc.subject COORDINATION POLYMERS ko
dc.subject SOLID-STATE ko
dc.subject STRUCTURAL TRANSFORMATIONS ko
dc.subject GUEST REMOVAL ko
dc.subject CARBON-DIOXIDE ko
dc.subject HYDROGEN ko
dc.subject ADSORPTION ko
dc.subject EXCHANGE ko
dc.subject DYNAMICS ko
dc.title Crystal-to-Crystal Transformations of a Series of Isostructural Metal-Organic Frameworks with Different Sizes of Ligated Solvent Molecules ko
dc.type ARTICLE ko
dc.identifier.scopusid 2-s2.0-84875764429 ko
dc.identifier.wosid 000317094300053 ko
dc.type.rims ART ko
dc.description.scopustc 5 *
dc.date.scptcdate 2014-07-12 *
dc.identifier.doi 10.1021/ic302641v ko
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