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Lah, Myoung Soo
Frontier Energy Storage Material Lab.
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dc.citation.endPage 3899 -
dc.citation.number 7 -
dc.citation.startPage 3891 -
dc.citation.title INORGANIC CHEMISTRY -
dc.citation.volume 52 -
dc.contributor.author Oh, Minhak -
dc.contributor.author Rajput, Lalit -
dc.contributor.author Kim, Dongwook -
dc.contributor.author Moon, Dohyun -
dc.contributor.author Lah, Myoung Soo -
dc.date.accessioned 2023-12-22T04:08:43Z -
dc.date.available 2023-12-22T04:08:43Z -
dc.date.created 2013-07-01 -
dc.date.issued 2013-04 -
dc.description.abstract Isostructural 3D metal-organic frameworks (MOFs) [Zn-2(BTC)(NO3)S-3] [where BTC = 1,3,5-benzenetricarboxylate; S = EtOH (1), DMF (2), DMA (3), or DEF (4)] of a 3-connected srs net topology have been prepared in the presence of serine as a template. The MOFs show different framework stabilities depending on the sizes of the ligated solvent molecules and undergo a crystal-to-crystal transformation at ambient conditions into a ID chain structure either directly or via different types of intermediates depending on the ligated solvent molecules and the sample handling conditions. A single crystal of the MOF with the ligated DMF molecules, [Zn-2(BTC)(NO3)(DMF)(3)] (2), is stable in Mg-II- and Co-II-DMF solutions; however, it transforms into a sing,le particle-like microcrystalline aggregate of Cu-HKUST-1 in a Cu-II-DMF solution. -
dc.identifier.bibliographicCitation INORGANIC CHEMISTRY, v.52, no.7, pp.3891 - 3899 -
dc.identifier.doi 10.1021/ic302641v -
dc.identifier.issn 0020-1669 -
dc.identifier.scopusid 2-s2.0-84875764429 -
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/3379 -
dc.identifier.url http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84875764429 -
dc.identifier.wosid 000317094300053 -
dc.language 영어 -
dc.publisher AMER CHEMICAL SOC -
dc.title Crystal-to-Crystal Transformations of a Series of Isostructural Metal-Organic Frameworks with Different Sizes of Ligated Solvent Molecules -
dc.type Article -
dc.relation.journalWebOfScienceCategory Chemistry, Inorganic & Nuclear -
dc.relation.journalResearchArea Chemistry -
dc.description.journalRegisteredClass scie -
dc.description.journalRegisteredClass scopus -
dc.subject.keywordPlus INDUCED SINGLE-CRYSTAL -
dc.subject.keywordPlus COORDINATION POLYMERS -
dc.subject.keywordPlus SOLID-STATE -
dc.subject.keywordPlus STRUCTURAL TRANSFORMATIONS -
dc.subject.keywordPlus GUEST REMOVAL -
dc.subject.keywordPlus CARBON-DIOXIDE -
dc.subject.keywordPlus HYDROGEN -
dc.subject.keywordPlus ADSORPTION -
dc.subject.keywordPlus EXCHANGE -
dc.subject.keywordPlus DYNAMICS -

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