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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 16515 | - |
dc.citation.number | 51 | - |
dc.citation.startPage | 16514 | - |
dc.citation.title | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.volume | 128 | - |
dc.contributor.author | Sanderson, Matthew D. | - |
dc.contributor.author | Kamplain, Justin W. | - |
dc.contributor.author | Bielawski, Christopher W. | - |
dc.date.accessioned | 2023-12-22T09:38:49Z | - |
dc.date.available | 2023-12-22T09:38:49Z | - |
dc.date.created | 2020-07-13 | - |
dc.date.issued | 2006-12 | - |
dc.description.abstract | A new N-heterocyclic carbene architecture comprising a 1,4-naphthoquinone annulated to 1,3-dimesitylimidazolylidene (NpQ−NHC) was synthesized in two high yielding steps from commercially available starting materials. The free NpQ−NHC was characterized (solution and solid-state) and was used to synthesize various Rh and Ag complexes that ranged in π-electron density. Enabled by the quinone moiety, the π-systems of these complexes were analyzed using infrared spectroscopy and cyclic voltammetry. In contrast to previous reports, π-backbonding was found to be non-negligible and was directly influenced by the metal's electronic character. | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.128, no.51, pp.16514 - 16515 | - |
dc.identifier.doi | 10.1021/ja067475w | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.scopusid | 2-s2.0-33845929780 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/33300 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/ja067475w | - |
dc.identifier.wosid | 000242941600051 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Quinone-annulated N-heterocyclic carbene-transition-metal complexes: Observation of pi-backbonding using FT-IR spectroscopy and cyclic voltammetry | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | STABLE CARBENES | - |
dc.subject.keywordPlus | GAMMA-BUTYROLACTONES | - |
dc.subject.keywordPlus | ANELLATION | - |
dc.subject.keywordPlus | CATALYSIS | - |
dc.subject.keywordPlus | ALDEHYDES | - |
dc.subject.keywordPlus | POLYMERS | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordPlus | NHCS | - |
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