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DC Field | Value | Language |
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dc.citation.endPage | 6514 | - |
dc.citation.number | 26 | - |
dc.citation.startPage | 6511 | - |
dc.citation.title | ORGANOMETALLICS | - |
dc.citation.volume | 26 | - |
dc.contributor.author | Martinez-Garcia, Hector | - |
dc.contributor.author | Morales, Dolores | - |
dc.contributor.author | Perez, Julio | - |
dc.contributor.author | Coady, Daniel J. | - |
dc.contributor.author | Bielawski, Christopher W. | - |
dc.contributor.author | Gross, Dustin E. | - |
dc.contributor.author | Cuesta, Luciano | - |
dc.contributor.author | Marquez, Manuel | - |
dc.contributor.author | Sessler, Jonathan L. | - |
dc.date.accessioned | 2023-12-22T09:07:10Z | - |
dc.date.available | 2023-12-22T09:07:10Z | - |
dc.date.created | 2020-07-13 | - |
dc.date.issued | 2007-12 | - |
dc.description.abstract | Calix[4]pyrrole, an easy-to-prepare anion receptor, acts to promote the cuprous chloride-catalyzed aziridination of styrene by the nitrene source chloramine-T in acetonitrile. The mechanism of action is believed to involve incipient anion-receptor interactions involving the calix[4]pyrrole NH protons and the chlorine atom of the CuCl, rather than direct bonding to, and activation of, the chloramine-T Consistent with this supposition were the findings that (1) the use of calix[4]pyrrole, in combination with CuCl, did promote enhanced reactivity when PhI=NTs was used as the nitrene source and (2) the presence of calix[4]pyrrole had no effect on the reaction when Cul was used as a catalyst. Decreased yields were also seen with CuCl2, and no appreciable aziridination product was observed when the calix[4]pyrrole was replaced by an appropriately chosen dipyrromethane control compound. On the other hand, the enhancement effect provided by calix[4]pyrrole proved relatively insensitive to the presence of trace quantities of water. | - |
dc.identifier.bibliographicCitation | ORGANOMETALLICS, v.26, no.26, pp.6511 - 6514 | - |
dc.identifier.doi | 10.1021/om700958c | - |
dc.identifier.issn | 0276-7333 | - |
dc.identifier.scopusid | 2-s2.0-38049150123 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/33289 | - |
dc.identifier.url | https://pubs.acs.org/doi/abs/10.1021/om700958c | - |
dc.identifier.wosid | 000251547000003 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Calix[4]pyrrole as a promoter of the CuCl-catalyzed reaction of styrene and chloramine-T | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear; Chemistry, Organic | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | EFFICIENT AZIRIDINATION | - |
dc.subject.keywordPlus | OLEFIN AZIRIDINATION | - |
dc.subject.keywordPlus | NITRENE TRANSFER | - |
dc.subject.keywordPlus | ALKENES | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | COPPER(I) | - |
dc.subject.keywordPlus | ORGANOCATALYSIS | - |
dc.subject.keywordPlus | RECOGNITION | - |
dc.subject.keywordPlus | CHLORIDE | - |
dc.subject.keywordPlus | CORROLE | - |
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