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- Bielawski, Christopher W.
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| DC Field | Value | Language |
|---|---|---|
| dc.citation.endPage | 6862 | - |
| dc.citation.number | 29 | - |
| dc.citation.startPage | 6853 | - |
| dc.citation.title | TETRAHEDRON | - |
| dc.citation.volume | 64 | - |
| dc.contributor.author | Khramov, Dimitri M. | - |
| dc.contributor.author | Rosen, Evelyn L. | - |
| dc.contributor.author | Er, Joyce An. | - |
| dc.contributor.author | Vu, Peter D. | - |
| dc.contributor.author | Lynch, Vincent M. | - |
| dc.contributor.author | Bielawski, Christopher W. | - |
| dc.date.accessioned | 2023-12-22T08:37:57Z | - |
| dc.date.available | 2023-12-22T08:37:57Z | - |
| dc.date.created | 2020-07-13 | - |
| dc.date.issued | 2008-07 | - |
| dc.description.abstract | The effect of tuning the electronic properties of N-heterocyclic carbene (NHC) ligands was evaluated in multiple, mechanistically distinct, metal-mediated reactions. Hydroboration and Heck reactions, catalyzed by Rh-NHC and Pd-NHC complexes, respectively, were found to result in yields that were up to ten times lower when pi-withdrawing substituents were incorporated into the NHC backbone relative to analogues bearing sigma-withdrawing groups. | - |
| dc.identifier.bibliographicCitation | TETRAHEDRON, v.64, no.29, pp.6853 - 6862 | - |
| dc.identifier.doi | 10.1016/j.tet.2008.04.030 | - |
| dc.identifier.issn | 0040-4020 | - |
| dc.identifier.scopusid | 2-s2.0-44949203422 | - |
| dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/33280 | - |
| dc.identifier.url | https://www.sciencedirect.com/science/article/pii/S004040200800714X?via%3Dihub | - |
| dc.identifier.wosid | 000257790300005 | - |
| dc.language | 영어 | - |
| dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
| dc.title | N-heterocyclic carbenes: deducing sigma- and pi-contributions in Rh-catalyzed hydroboration and Pd-catalyzed coupling reactions | - |
| dc.type | Article | - |
| dc.description.isOpenAccess | FALSE | - |
| dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
| dc.relation.journalResearchArea | Chemistry | - |
| dc.type.docType | Review | - |
| dc.description.journalRegisteredClass | scie | - |
| dc.description.journalRegisteredClass | scopus | - |
| dc.subject.keywordPlus | TRANSITION-METAL-COMPLEXES | - |
| dc.subject.keywordPlus | CHAIN ORGANOMETALLIC POLYMERS | - |
| dc.subject.keywordPlus | OLEFIN METATHESIS CATALYSTS | - |
| dc.subject.keywordPlus | SUZUKI-MIYAURA | - |
| dc.subject.keywordPlus | ELECTRONIC-PROPERTIES | - |
| dc.subject.keywordPlus | ARYL CHLORIDES | - |
| dc.subject.keywordPlus | NHC LIGANDS | - |
| dc.subject.keywordPlus | DEHYDROGENATIVE BORYLATION | - |
| dc.subject.keywordPlus | (NHC)PD(ALLYL)CL NHC | - |
| dc.subject.keywordPlus | SELECTIVE SYNTHESIS | - |
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