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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 16636 | - |
dc.citation.number | 46 | - |
dc.citation.startPage | 16631 | - |
dc.citation.title | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.volume | 132 | - |
dc.contributor.author | Tennyson, Andrew G. | - |
dc.contributor.author | Wiggins, Kelly M. | - |
dc.contributor.author | Bielawski, Christopher W. | - |
dc.date.accessioned | 2023-12-22T06:39:54Z | - |
dc.date.available | 2023-12-22T06:39:54Z | - |
dc.date.created | 2020-07-13 | - |
dc.date.issued | 2010-11 | - |
dc.description.abstract | Coupling of pyridine-capped poly(methyl acrylate)s, PyPM (where M corresponds to the number average molecular weight in kDa), to the SCS-cyclometalated dipalladium complex [(1)(CH3CN)2] afforded organometallic polymers [(1)(PyPM)(2)] with a concomitant doubling in molecular weight. Ultrasonication of solutions containing [(1)(PyPM)(2)] effected the mechanical scission of a palladium-pyridine bond, where the liberated PyPM was trapped with excess HBF4 as the corresponding pyridinium salt, harnessed to effect the stoichiometric deprotonation of a colorimetric indicator, or used to catalyze the anionic polymerization of alpha-trifluoromethyl-2,2,2-trifluoroethyl acrylate. The mechanically induced chain scission also unmasked a catalytically active palladium species which was used to facilitate carbon-carbon bond formation between benzyl cyanide and N-tosyl imines. Spectroscopic and macromolecular analyses as well as a series of control experiments demonstrated that the aforementioned structural changes were derived from mechanical forces that originated from ultrasound-induced dissociation of the polymer chains connected to the aforementioned Pd complexes. | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.132, no.46, pp.16631 - 16636 | - |
dc.identifier.doi | 10.1021/ja107620y | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.scopusid | 2-s2.0-78649290993 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/33221 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/ja107620y | - |
dc.identifier.wosid | 000284792000056 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Mechanical Activation of Catalysts for C-C Bond Forming and Anionic Polymerization Reactions from a Single Macromolecular Reagent | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | SELF-HEALING MATERIALS | - |
dc.subject.keywordPlus | COORDINATION POLYMERS | - |
dc.subject.keywordPlus | CHAIN SCISSION | - |
dc.subject.keywordPlus | PINCER | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | FORCE | - |
dc.subject.keywordPlus | FUNCTIONALIZATION | - |
dc.subject.keywordPlus | SONOCHEMISTRY | - |
dc.subject.keywordPlus | COPOLYMERS | - |
dc.subject.keywordPlus | NITRILES | - |
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