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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 304 | - |
dc.citation.number | 1 | - |
dc.citation.startPage | 301 | - |
dc.citation.title | JOURNAL OF ORGANIC CHEMISTRY | - |
dc.citation.volume | 76 | - |
dc.contributor.author | Norris, Brent C. | - |
dc.contributor.author | Sheppard, Daniel G. | - |
dc.contributor.author | Henkelman, Graeme | - |
dc.contributor.author | Bielawski, Christopher W. | - |
dc.date.accessioned | 2023-12-22T06:36:48Z | - |
dc.date.available | 2023-12-22T06:36:48Z | - |
dc.date.created | 2020-07-13 | - |
dc.date.issued | 2011-01 | - |
dc.description.abstract | Using stopped flow and other spectroscopic techniques, the thermodynamic parameters of the coupling reaction between 1,3-dimesitylimidazolylidene and phenyl isothiocyanate were determined (H degrees = 96.1 kJ mol(-1) and Delta S degrees = 39.6 J mol(-1) K-1). On the basis of these data which indicated that the reaction was reversible (K-eq = 5.94 x 10(14) M-1 at 25 degrees C; k(r) = 252 M-1 s(-1); k(r) = 4.24 x 10(-13) s(-1)), the adduct formed from the two aforementioned coupling partners was used as a latent catalyst to facilitate the [2 + 2 + 2] cyclotrimerization of phenyl isocyanate and the polymerization of DL-lactide. | - |
dc.identifier.bibliographicCitation | JOURNAL OF ORGANIC CHEMISTRY, v.76, no.1, pp.301 - 304 | - |
dc.identifier.doi | 10.1021/jo101850g | - |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.scopusid | 2-s2.0-78650877485 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/33205 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/jo101850g | - |
dc.identifier.wosid | 000285704000037 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Kinetic and Thermodynamic Evaluation of the Reversible N-Heterocyclic Carbene-lsothiocyanate Coupling Reaction: Applications in Latent Catalysis | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | RING-OPENING POLYMERIZATION | - |
dc.subject.keywordPlus | INITIO MOLECULAR-DYNAMICS | - |
dc.subject.keywordPlus | LIVING POLYMERIZATION | - |
dc.subject.keywordPlus | HIGHLY EFFICIENT | - |
dc.subject.keywordPlus | PRECURSORS | - |
dc.subject.keywordPlus | IMIDAZOL(IN)IUM-2-CARBOXYLATES | - |
dc.subject.keywordPlus | ISOTHIOCYANATES | - |
dc.subject.keywordPlus | CYCLOADDITION | - |
dc.subject.keywordPlus | METATHESIS | - |
dc.subject.keywordPlus | STABILITY | - |
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