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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 1426 | - |
dc.citation.number | 6 | - |
dc.citation.startPage | 1421 | - |
dc.citation.title | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | - |
dc.citation.volume | 49 | - |
dc.contributor.author | Chen, Zheng | - |
dc.contributor.author | Dreyer, Daniel R. | - |
dc.contributor.author | Wu, Zong-Quan | - |
dc.contributor.author | Wiggins, Kelly M. | - |
dc.contributor.author | Jiang, Zhenhua | - |
dc.contributor.author | Bielawski, Christopher W. | - |
dc.date.accessioned | 2023-12-22T06:14:21Z | - |
dc.date.available | 2023-12-22T06:14:21Z | - |
dc.date.created | 2020-07-13 | - |
dc.date.issued | 2011-03 | - |
dc.description.abstract | The synthesis and characterized con of a novel family of main-chain carbazole-containing polymers using copper-cat-alyzed azide-alkyne cycloaddition chemistry is reported. The reactions were performed under mild conditions using readily available copper catalysts and ligands, which afforded polymeric products with M(w)s up to 18 kDa. Using a range of techniques, the polymers were found to exhibit a glass transition temperature (T-g) of 85 degrees C, high thermal stability (T-d = 274 degrees C), and high photoluminescent quantum efficiency (Phi(f) = 0.29; lambda(em) = 448 nm), which underscore their potential for use in organic light-emitting diodes or other emissive devices, particularly where efficient blue emission is of value. The approach described offers practical advantages over other synthetic methods used to prepare main-chain carbazole-containing polymers, especially with regard to the lack of need for rigorously inert conditions and the absence of byproducts generated during the polymerization reaction. | - |
dc.identifier.bibliographicCitation | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, v.49, no.6, pp.1421 - 1426 | - |
dc.identifier.doi | 10.1002/pola.24563 | - |
dc.identifier.issn | 0887-624X | - |
dc.identifier.scopusid | 2-s2.0-79851499119 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/33195 | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/full/10.1002/pola.24563 | - |
dc.identifier.wosid | 000288465600013 | - |
dc.language | 영어 | - |
dc.publisher | WILEY | - |
dc.title | Synthesis of Main-Chain Poly(carbazole)s via CuAAC | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Polymer Science | - |
dc.relation.journalResearchArea | Polymer Science | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | alkyne | - |
dc.subject.keywordAuthor | azide | - |
dc.subject.keywordAuthor | carbazole | - |
dc.subject.keywordAuthor | click chemistry | - |
dc.subject.keywordAuthor | copper | - |
dc.subject.keywordAuthor | fluorescence | - |
dc.subject.keywordAuthor | photophysics | - |
dc.subject.keywordAuthor | step-growth polymerization | - |
dc.subject.keywordAuthor | synthesis | - |
dc.subject.keywordAuthor | thermogravimetric analysis | - |
dc.subject.keywordPlus | CARBAZOLE-CONTAINING SYSTEMS | - |
dc.subject.keywordPlus | CLICK-CHEMISTRY | - |
dc.subject.keywordPlus | N-VINYLCARBAZOLE | - |
dc.subject.keywordPlus | SOLAR-CELLS | - |
dc.subject.keywordPlus | ELECTROLUMINESCENT POLYMERS | - |
dc.subject.keywordPlus | POLY(N-VINYL CARBAZOLE) | - |
dc.subject.keywordPlus | TERMINAL ALKYNES | - |
dc.subject.keywordPlus | DILUTE-SOLUTION | - |
dc.subject.keywordPlus | TRIPLET ENERGY | - |
dc.subject.keywordPlus | POLYMERIZATION | - |
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