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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 3245 | - |
dc.citation.number | 9 | - |
dc.citation.startPage | 3239 | - |
dc.citation.title | JOURNAL OF ORGANIC CHEMISTRY | - |
dc.citation.volume | 76 | - |
dc.contributor.author | Ono, Robert J. | - |
dc.contributor.author | Suzuki, Yasuo | - |
dc.contributor.author | Khramov, Dimitri M. | - |
dc.contributor.author | Ueda, Mitsuru | - |
dc.contributor.author | Sessler, Jonathan L. | - |
dc.contributor.author | Bielawski, Christopher W. | - |
dc.date.accessioned | 2023-12-22T06:10:00Z | - |
dc.date.available | 2023-12-22T06:10:00Z | - |
dc.date.created | 2020-07-13 | - |
dc.date.issued | 2011-05 | - |
dc.description.abstract | Coupling of various 4-substituted phenyl azides with two distinct quinone-containing N-heterocyclic carbenes (NHCs) afforded the respective mono- and ditopic 1,3-disubstituted acyclic triazenes in moderate to excellent yields (38-92%). Depending on their pendant substituents (derived from the azides), the acyclic triazenes exhibited intense absorptions in the visible spectrum (359-428 nm), which were bathochromically shifted by up to Delta lambda = 68 nm upon reduction of the quinone moiety on the component derived from the NHC. Cyclic voltammetry confirmed that the aforementioned redox processes were reversible, and a related set of UV-vis spectroelectrochemical experiments revealed that bulk electrolysis may also be used to switch reversibly the colors exhibited by these triazenes. | - |
dc.identifier.bibliographicCitation | JOURNAL OF ORGANIC CHEMISTRY, v.76, no.9, pp.3239 - 3245 | - |
dc.identifier.doi | 10.1021/jo200139f | - |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.scopusid | 2-s2.0-79955556127 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/33189 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/jo200139f | - |
dc.identifier.wosid | 000289956900029 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Synthesis and Study of Redox-Active Acyclic Triazenes: Toward Electrochromic Applications | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | BIS(N-HETEROCYCLIC CARBENE) | - |
dc.subject.keywordPlus | METAL-COMPLEXES | - |
dc.subject.keywordPlus | TUNGSTEN-OXIDE | - |
dc.subject.keywordPlus | POLYMERS | - |
dc.subject.keywordPlus | DEVICES | - |
dc.subject.keywordPlus | FILMS | - |
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