There are no files associated with this item.
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 1609 | - |
dc.citation.number | 6049 | - |
dc.citation.startPage | 1606 | - |
dc.citation.title | SCIENCE | - |
dc.citation.volume | 333 | - |
dc.contributor.author | Brantley, Johnathan N. | - |
dc.contributor.author | Wiggins, Kelly M. | - |
dc.contributor.author | Bielawski, Christopher W. | - |
dc.date.accessioned | 2023-12-22T05:45:14Z | - |
dc.date.available | 2023-12-22T05:45:14Z | - |
dc.date.created | 2020-07-13 | - |
dc.date.issued | 2011-09 | - |
dc.description.abstract | The specific targeting of covalent bonds in a local, anisotropic fashion using mechanical methods offers useful opportunities to direct chemical reactivity down otherwise prohibitive pathways. Here, we report that embedding the highly inert 1,2,3-triazole moiety (which is often prepared using the canonical "click" coupling of azides and alkynes) within a poly(methyl acrylate) chain renders it susceptible to ultrasound-induced cycloreversion, as confirmed by comprehensive spectroscopic and chemical analyses. Such reactivity offers the opportunity to develop triazoles as mechanically labile protecting groups or for use in readily accessible materials that respond to mechanical force. | - |
dc.identifier.bibliographicCitation | SCIENCE, v.333, no.6049, pp.1606 - 1609 | - |
dc.identifier.doi | 10.1126/science.1207934 | - |
dc.identifier.issn | 0036-8075 | - |
dc.identifier.scopusid | 2-s2.0-80052942899 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/33180 | - |
dc.identifier.url | https://science.sciencemag.org/content/333/6049/1606 | - |
dc.identifier.wosid | 000294900900036 | - |
dc.language | 영어 | - |
dc.publisher | AMER ASSOC ADVANCEMENT SCIENCE | - |
dc.title | Unclicking the Click: Mechanically Facilitated 1,3-Dipolar Cycloreversions | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Multidisciplinary Sciences | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | TERMINAL ALKYNES | - |
dc.subject.keywordPlus | OLIGONUCLEOTIDES | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | AZIDES | - |
dc.subject.keywordPlus | FORCE | - |
dc.subject.keywordPlus | MECHANOCHEMISTRY | - |
dc.subject.keywordPlus | CYCLOADDITION | - |
dc.subject.keywordPlus | STRESS | - |
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Tel : 052-217-1404 / Email : scholarworks@unist.ac.kr
Copyright (c) 2023 by UNIST LIBRARY. All rights reserved.
ScholarWorks@UNIST was established as an OAK Project for the National Library of Korea.