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BielawskiChristopher W

Bielawski, Christopher W.
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dc.citation.endPage 10326 -
dc.citation.number 44 -
dc.citation.startPage 10322 -
dc.citation.title ANGEWANDTE CHEMIE-INTERNATIONAL EDITION -
dc.citation.volume 50 -
dc.contributor.author Neilson, Bethany M. -
dc.contributor.author Lynch, Vincent M. -
dc.contributor.author Bielawski, Christopher W. -
dc.date.accessioned 2023-12-22T05:42:26Z -
dc.date.available 2023-12-22T05:42:26Z -
dc.date.created 2020-07-13 -
dc.date.issued 2011-10 -
dc.description.abstract Ligands in the limelight : Light was used to change the electron‐donating properties of an N‐heterocyclic carbene (NHC) moiety within chalcogen and metal adducts. Photoinduced electrocyclic ring closure of a photochromic 4,5‐dithienylimidazolone increased its νCO frequency. Likewise, UV irradiation of an analogous photochromic [(NHC)Ir(CO)2Cl] complex decreased the carbene's electron‐donating ability. Subsequent exposure to visible light reversed both photocyclization reactions. -
dc.identifier.bibliographicCitation ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.50, no.44, pp.10322 - 10326 -
dc.identifier.doi 10.1002/anie.201105032 -
dc.identifier.issn 1433-7851 -
dc.identifier.scopusid 2-s2.0-80054999132 -
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/33176 -
dc.identifier.url https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201105032 -
dc.identifier.wosid 000297049300008 -
dc.language 영어 -
dc.publisher WILEY-V C H VERLAG GMBH -
dc.title Photoswitchable N-Heterocyclic Carbenes: Using Light to Modulate Electron-Donating Properties -
dc.type Article -
dc.description.isOpenAccess FALSE -
dc.relation.journalWebOfScienceCategory Chemistry, Multidisciplinary -
dc.relation.journalResearchArea Chemistry -
dc.type.docType Article -
dc.description.journalRegisteredClass scie -
dc.description.journalRegisteredClass scopus -
dc.subject.keywordAuthor carbenes -
dc.subject.keywordAuthor cyclization -
dc.subject.keywordAuthor nitrogen heterocycles -
dc.subject.keywordAuthor photochromism -
dc.subject.keywordAuthor photoswitch -
dc.subject.keywordPlus SINGLE-CRYSTALLINE PHASE -
dc.subject.keywordPlus OLEFIN METATHESIS CATALYSTS -
dc.subject.keywordPlus TRANSITION-METAL-COMPLEXES -
dc.subject.keywordPlus PHOTOCHROMIC PROPERTIES -
dc.subject.keywordPlus DITHIENYLETHENE DTE -
dc.subject.keywordPlus COORDINATION CHEMISTRY -
dc.subject.keywordPlus DONOR PROPERTIES -
dc.subject.keywordPlus MOLECULAR WIRE -
dc.subject.keywordPlus DIARYLETHENE -
dc.subject.keywordPlus SWITCHES -

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