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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 10326 | - |
dc.citation.number | 44 | - |
dc.citation.startPage | 10322 | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 50 | - |
dc.contributor.author | Neilson, Bethany M. | - |
dc.contributor.author | Lynch, Vincent M. | - |
dc.contributor.author | Bielawski, Christopher W. | - |
dc.date.accessioned | 2023-12-22T05:42:26Z | - |
dc.date.available | 2023-12-22T05:42:26Z | - |
dc.date.created | 2020-07-13 | - |
dc.date.issued | 2011-10 | - |
dc.description.abstract | Ligands in the limelight : Light was used to change the electron‐donating properties of an N‐heterocyclic carbene (NHC) moiety within chalcogen and metal adducts. Photoinduced electrocyclic ring closure of a photochromic 4,5‐dithienylimidazolone increased its νCO frequency. Likewise, UV irradiation of an analogous photochromic [(NHC)Ir(CO)2Cl] complex decreased the carbene's electron‐donating ability. Subsequent exposure to visible light reversed both photocyclization reactions. | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.50, no.44, pp.10322 - 10326 | - |
dc.identifier.doi | 10.1002/anie.201105032 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.scopusid | 2-s2.0-80054999132 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/33176 | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201105032 | - |
dc.identifier.wosid | 000297049300008 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Photoswitchable N-Heterocyclic Carbenes: Using Light to Modulate Electron-Donating Properties | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | carbenes | - |
dc.subject.keywordAuthor | cyclization | - |
dc.subject.keywordAuthor | nitrogen heterocycles | - |
dc.subject.keywordAuthor | photochromism | - |
dc.subject.keywordAuthor | photoswitch | - |
dc.subject.keywordPlus | SINGLE-CRYSTALLINE PHASE | - |
dc.subject.keywordPlus | OLEFIN METATHESIS CATALYSTS | - |
dc.subject.keywordPlus | TRANSITION-METAL-COMPLEXES | - |
dc.subject.keywordPlus | PHOTOCHROMIC PROPERTIES | - |
dc.subject.keywordPlus | DITHIENYLETHENE DTE | - |
dc.subject.keywordPlus | COORDINATION CHEMISTRY | - |
dc.subject.keywordPlus | DONOR PROPERTIES | - |
dc.subject.keywordPlus | MOLECULAR WIRE | - |
dc.subject.keywordPlus | DIARYLETHENE | - |
dc.subject.keywordPlus | SWITCHES | - |
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