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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 881 | - |
dc.citation.number | 4 | - |
dc.citation.startPage | 874 | - |
dc.citation.title | POLYMER CHEMISTRY | - |
dc.citation.volume | 3 | - |
dc.contributor.author | Wu, Zong-Quan | - |
dc.contributor.author | Radcliffe, Jonathan D. | - |
dc.contributor.author | Ono, Robert J. | - |
dc.contributor.author | Chen, Zheng | - |
dc.contributor.author | Li, Zicheng | - |
dc.contributor.author | Bielawski, Christopher W. | - |
dc.date.accessioned | 2023-12-22T05:37:56Z | - |
dc.date.available | 2023-12-22T05:37:56Z | - |
dc.date.created | 2020-07-10 | - |
dc.date.issued | 2012 | - |
dc.description.abstract | Block copolymers comprised of poly(3-hexylthiophene) and three different poly(isocyanide)s were synthesized in a single pot via the sequential addition of 2-bromo-3-hexyl-5-chloromagnesiothiophene followed by 2-(2-methoxyethoxy) ethyl 4-isocyanobenzoate, tert-butyl 4-isocyanobenzoate, or 1-isocyanohexadecane to a solution of 1,3-bis(diphenylphosphino) propane dichloronickel. Similarly, block copolymers of poly(1-dodecylpyrrole) along with poly(2,5-bis(hexyloxy) phenylene) and a poly(arylisocyanide) were also prepared using an analogous methodology. The respective mechanistically distinct polymerizations proceeded in a controlled fashion, were mediated by a common catalyst, and afforded well-defined block copolymers with tunable molecular weights and compositions. Selected block copolymers exhibited higher-order structures in solution and microphase separation characteristics in the solid state. | - |
dc.identifier.bibliographicCitation | POLYMER CHEMISTRY, v.3, no.4, pp.874 - 881 | - |
dc.identifier.doi | 10.1039/c2py00566b | - |
dc.identifier.issn | 1759-9954 | - |
dc.identifier.scopusid | 2-s2.0-84863269980 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/33167 | - |
dc.identifier.url | https://pubs.rsc.org/en/content/articlelanding/2012/PY/c2py00566b#!divAbstract | - |
dc.identifier.wosid | 000301199600009 | - |
dc.language | 영어 | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Synthesis of conjugated diblock copolymers: two mechanistically distinct, sequential living polymerizations using a single catalyst | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Polymer Science | - |
dc.relation.journalResearchArea | Polymer Science | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | CHAIN-GROWTH POLYMERIZATIONS | - |
dc.subject.keywordPlus | GRIGNARD METATHESIS METHOD | - |
dc.subject.keywordPlus | BLOCK-COPOLYMERS | - |
dc.subject.keywordPlus | TRANSFER POLYCONDENSATION | - |
dc.subject.keywordPlus | LOW POLYDISPERSITY | - |
dc.subject.keywordPlus | MOLECULAR-WEIGHT | - |
dc.subject.keywordPlus | PHASE-SEPARATION | - |
dc.subject.keywordPlus | SOLAR-CELLS | - |
dc.subject.keywordPlus | SIDE-CHAIN | - |
dc.subject.keywordPlus | POLYTHIOPHENE | - |
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