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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 6435 | - |
dc.citation.number | 15 | - |
dc.citation.startPage | 6428 | - |
dc.citation.title | LANGMUIR | - |
dc.citation.volume | 28 | - |
dc.contributor.author | Dreyer, Daniel R. | - |
dc.contributor.author | Miller, Daniel J. | - |
dc.contributor.author | Freeman, Benny D. | - |
dc.contributor.author | Paul, Donald R. | - |
dc.contributor.author | Bielawski, Christopher W. | - |
dc.date.accessioned | 2023-12-22T05:11:16Z | - |
dc.date.available | 2023-12-22T05:11:16Z | - |
dc.date.created | 2020-07-10 | - |
dc.date.issued | 2012-04 | - |
dc.description.abstract | Herein we propose a new structure for poly(dopamine), a synthetic eumelanin that has found broad utility as an antifouling agent. Commercially available 3-hydroxytyramine hydrochloride (dopamine HCl) was polymerized under aerobic, aqueous conditions using tris(hydroxymethyl)aminomethane (TRIS) as a basic polymerization initiator, affording a darkly colored powder product upon isolation. The polymer was analyzed using a variety of solid state spectroscopic and crystallographic techniques. Collectively, the data showed that in contrast to previously proposed models, poly(dopamine) is not a covalent polymer but instead a supramolecular aggregate of monomers (consisting primarily of 5,6-dihydroxyindoline and its dione derivative) that are held together through a combination of charge transfer, pi-stacking, and hydrogen bonding interactions. | - |
dc.identifier.bibliographicCitation | LANGMUIR, v.28, no.15, pp.6428 - 6435 | - |
dc.identifier.doi | 10.1021/la204831b | - |
dc.identifier.issn | 0743-7463 | - |
dc.identifier.scopusid | 2-s2.0-84859922140 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/33146 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/la204831b | - |
dc.identifier.wosid | 000302852200028 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Elucidating the Structure of Poly(dopamine) | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary; Chemistry, Physical; Materials Science, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry; Materials Science | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | SOLID-STATE NMR | - |
dc.subject.keywordPlus | PI-PI STACKING | - |
dc.subject.keywordPlus | OXIDATIVE POLYMERIZATION | - |
dc.subject.keywordPlus | RADICAL CYCLIZATION | - |
dc.subject.keywordPlus | MASS-SPECTROMETRY | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | CARBON NANOTUBES | - |
dc.subject.keywordPlus | DOUBLE-RESONANCE | - |
dc.subject.keywordPlus | CELL-ADHESION | - |
dc.subject.keywordPlus | MELANIN | - |
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