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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 1935 | - |
dc.citation.number | 6 | - |
dc.citation.startPage | 1929 | - |
dc.citation.title | MACROMOLECULES | - |
dc.citation.volume | 33 | - |
dc.contributor.author | Maughon, BR | - |
dc.contributor.author | Morita, T | - |
dc.contributor.author | Bielawski, CW | - |
dc.contributor.author | Grubbs, RH | - |
dc.date.accessioned | 2023-12-22T12:08:03Z | - |
dc.date.available | 2023-12-22T12:08:03Z | - |
dc.date.created | 2020-07-13 | - |
dc.date.issued | 2000-03 | - |
dc.description.abstract | The synthesis of ring-opening metathesis polymerization (ROMP) chain transfer agents (CTA)s bearing methacrylate or epoxide end functionality was accomplished. In the presence of these CTAs, the ROMP of cyclooctadiene (COD) initiated with (PCy3)(2)Cl2Ru=CHPh afforded the respective telechelic poly(butenylene)s with either methacrylate or epoxide end groups. Control over the polymer molecular weight was demonstrated by varying the COD/CTA ratio; Successful cross-linking by thermal or photochemical initiation of the bis(methacrylate)-functionalized telechelic poly(butenylene)s or through acid catalysis of the bis(epoxide)-functionalized telechelic poly(butenylene)s was accomplished. While crosslinking was found to reduce solubility of the polymers, it greatly enhanced their thermal stability. | - |
dc.identifier.bibliographicCitation | MACROMOLECULES, v.33, no.6, pp.1929 - 1935 | - |
dc.identifier.doi | 10.1021/ma9907340 | - |
dc.identifier.issn | 0024-9297 | - |
dc.identifier.scopusid | 2-s2.0-0033870643 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/33070 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/ma9907340 | - |
dc.identifier.wosid | 000086073300005 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Synthesis of cross-linkable telechelic poly(butenylene)s derived from ring-opening metathesis polymerization | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Polymer Science | - |
dc.relation.journalResearchArea | Polymer Science | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | TRANSFER AGENTS INIFERS | - |
dc.subject.keywordPlus | SEQUENTIAL CO-POLYMERS | - |
dc.subject.keywordPlus | POLYBUTADIENE OLIGOMERS | - |
dc.subject.keywordPlus | ADMET DEPOLYMERIZATION | - |
dc.subject.keywordPlus | BORANE MONOMERS | - |
dc.subject.keywordPlus | CATALYSTS | - |
dc.subject.keywordPlus | RUCL2(=CHR&apos | - |
dc.subject.keywordPlus | )(PR(3))(2) | - |
dc.subject.keywordPlus | COPOLYMERS | - |
dc.subject.keywordPlus | OLEFINS | - |
dc.subject.keywordPlus | ETHERS | - |
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