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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 12497 | - |
dc.citation.number | 36 | - |
dc.citation.startPage | 12496 | - |
dc.citation.title | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.volume | 127 | - |
dc.contributor.author | Boydston, AJ | - |
dc.contributor.author | Williams, KA | - |
dc.contributor.author | Bielawski, CW | - |
dc.date.accessioned | 2023-12-22T10:12:45Z | - |
dc.date.available | 2023-12-22T10:12:45Z | - |
dc.date.created | 2020-07-13 | - |
dc.date.issued | 2005-09 | - |
dc.description.abstract | A highly efficient route to a new class of organometallic polymers containing difunctional N-heterocyclic carbenes has been developed. Bis(imidazolium) halides and divalent group X metals were copolymerized to afford organometallic polymers in up to quantitative yields and with molecular weights up to 106 Da, depending on the structure of the N-heterocyclic carbene and the incorporated transition metal. Enhanced solubilities were demonstrated through post-polymerization ligation with phosphines. Finally, selective end-group functionalization and excellent molecular weight control was achieved through the inclusion of monofunctional chain transfer agents during the polymerization. | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.127, no.36, pp.12496 - 12497 | - |
dc.identifier.doi | 10.1021/ja054029k | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.scopusid | 2-s2.0-24744448661 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/33059 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/ja054029k | - |
dc.identifier.wosid | 000232039100032 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | A modular approach to main-chain organometallic polymers | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | N-HETEROCYCLIC CARBENES | - |
dc.subject.keywordPlus | BIS(N-HETEROCYCLIC CARBENE) | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | METALLOPOLYMERS | - |
dc.subject.keywordPlus | REACTIVITY | - |
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