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Kim, Guntae
GUNS Lab
Research Interests
  • Solid Oxide Fuel Cells (SOFCs)& SOE, PEMFC, metal-air batteries, Metal-CO2 system

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Cation Swapping for High Power Density of SOFC

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Title
Cation Swapping for High Power Density of SOFC
Other Titles
SOFC 고전력밀도를위한양이온교환전략
Author
주상욱권오훈임채현김건태
Issue Date
2019-11-13
Publisher
한국세라믹학회
Citation
2019 한국세라믹학회 추계학술대회
Abstract
Exsolution has been intensively studied in the fields of energy conversion and storage as a method for the preparation of catalytically active and durable metal nanoparticles. Under typical conditions, however, only a limited number of nanoparticles can be exsolved from the host oxides. Herein, we report the first preparation of catalytic nanoparticles by selective exsolution through “topotactic ion exchange”, where deposited Fe guest cations can be exchanged with Co host cations in PrBaMn1.7Co0.3O5+. Interestingly, this phenomenon spontaneously yields the new host PrBaMn1.7Fe0.3O5+, liberating all the Co cations from the host owing to the favorable incorporation energy of Fe into the lattice of the parent host (∆Eincorporation= −0.41 eV) and the cation exchange energy (∆Eexchange= −0.34 eV). Remarkably, the increase in the number of exsolved nanoparticles leads to their improved catalytic activity as a SOFC electrode and in the dry reforming of methane.
URI
https://scholarworks.unist.ac.kr/handle/201301/32955
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