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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 397 | - |
dc.citation.number | 2 | - |
dc.citation.startPage | 392 | - |
dc.citation.title | NANO RESEARCH | - |
dc.citation.volume | 14 | - |
dc.contributor.author | Kim, Jiyeon | - |
dc.contributor.author | Nam, Dongsik | - |
dc.contributor.author | Kitagawa, Hiroshi | - |
dc.contributor.author | Lim, Dae-Woon | - |
dc.contributor.author | Choe, Wonyoung | - |
dc.date.accessioned | 2023-12-21T16:18:40Z | - |
dc.date.available | 2023-12-21T16:18:40Z | - |
dc.date.created | 2020-06-08 | - |
dc.date.issued | 2021-02 | - |
dc.description.abstract | Metal-based secondary building unit and the shape of organic ligands are the two crucial factors for determining the final topology of metal-organic materials. A careful choice of organic and inorganic structural building units occasionally produces unexpected structures, facilitating deeper fundamental understanding of coordination-driven self-assembly behind metal-organic materials. Here, we have synthesized a triangular metal-organic polygon (MOT-1), assembled from bulky tetramethyl terephthalate and Zr-based secondary building unit. Surprisingly, the Zr-based secondary building unit serves as an unusual ditopic Zr-connector, to form metal-organic polygon MOT-1, proven to be a good candidate for water adsorption with recyclability. This study highlights the interplay of the geometrically frustrated ligand and secondary building unit in controlling the connectivity of metal-organic polygon. Such a strategy can be further used to unveil a new class of metal-organic materials. | - |
dc.identifier.bibliographicCitation | NANO RESEARCH, v.14, no.2, pp.392 - 397 | - |
dc.identifier.doi | 10.1007/s12274-020-2830-9 | - |
dc.identifier.issn | 1998-0124 | - |
dc.identifier.scopusid | 2-s2.0-85085337040 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/32364 | - |
dc.identifier.url | https://link.springer.com/article/10.1007%2Fs12274-020-2830-9 | - |
dc.identifier.wosid | 000534954100003 | - |
dc.language | 영어 | - |
dc.publisher | TSINGHUA UNIV PRESS | - |
dc.title | Discovery of Zr-based metal-organic polygon: Unveiling new design opportunities in reticular chemistry | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied | - |
dc.relation.journalResearchArea | Chemistry; Science & Technology - Other Topics; Materials Science; Physics | - |
dc.type.docType | Article; Early Access | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | reticular chemistry | - |
dc.subject.keywordAuthor | Zr-based metal-organic polygon | - |
dc.subject.keywordAuthor | geometrical frustration | - |
dc.subject.keywordAuthor | ditopic | - |
dc.subject.keywordAuthor | secondary building unit | - |
dc.subject.keywordPlus | SUPRAMOLECULAR SQUARES | - |
dc.subject.keywordPlus | DINUCLEAR COMPLEXES | - |
dc.subject.keywordPlus | COORDINATION CAGES | - |
dc.subject.keywordPlus | WATER-ADSORPTION | - |
dc.subject.keywordPlus | BUILDING-BLOCKS | - |
dc.subject.keywordPlus | DIMETAL UNITS | - |
dc.subject.keywordPlus | FRAMEWORKS | - |
dc.subject.keywordPlus | MO-2(4+) | - |
dc.subject.keywordPlus | FUNCTIONALITY | - |
dc.subject.keywordPlus | CONSTRUCTION | - |
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