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Kwon, Tae-Hyuk
Energy Recognition
Research Interests
  • Energy transfer, organic solar cells, supercapacitor, ultrasonic spray chemistry, dithienothiophene, iridium complexes, phosphorescent bioapplications

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Dual-Functional Electrolyte Additives toward Long-Cycling Lithium-Ion Batteries : Ecofriendly Designed Carbonate Derivatives

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dc.contributor.author Han, Jung-Gu ko
dc.contributor.author Hwang, Eunbyul ko
dc.contributor.author Kim, Yoseph ko
dc.contributor.author Park, Sewon ko
dc.contributor.author Kim, Koeun ko
dc.contributor.author Roh, Deok-Ho ko
dc.contributor.author Gu, Minsu ko
dc.contributor.author Lee, Sang-Ho ko
dc.contributor.author Kwon, Tae-Hyuk ko
dc.contributor.author Kim, Youngjo ko
dc.contributor.author Choi, Nam-Soon ko
dc.contributor.author Kim, Byeong-Su ko
dc.date.available 2020-06-08T01:40:05Z -
dc.date.created 2020-06-01 ko
dc.date.issued 2020-05 ko
dc.identifier.citation ACS APPLIED MATERIALS & INTERFACES, v.12, no.21, pp.24479 - 24487 ko
dc.identifier.issn 1944-8244 ko
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/32328 -
dc.description.abstract Long-term stability of the solid electrolyte interphase (SEI) and cathode-electrolyte interface (CEI) layers formed on anodes and cathodes is imperative to mitigate the interfacial degradation of electrodes and enhance the cycle life of lithium-ion batteries (LIBs). However, the SEI on the anode and CEI on the cathode are vulnerable to the reactive species of PF5 and HF produced by the decomposition and hydrolysis of the conventional LiPF6 electrolyte in a battery inevitably containing a trace amount of water. Here, we report a new class of cyclic carbonate-based electrolyte additives to preserve the integrity of SEI and CEI in LIBs. This new class of additives is designed and synthesized by an ecofriendly approach that involves fixing CO2 with functional epoxides bearing various reactive side chains. It was found that the cyclic carbonates of 3-(1ethoxyethoxy)-1,2-propylene carbonate and 3-trimethoxysilylpropyloxy-1,2propylene carbonate, possessing high capability for the stabilization of Lewis-acidic PF5, exhibit a capacity retention of 79.0% after 1000 cycles, which is superior to that of the pristine electrolyte of 54.7%. Moreover, TMSPC has HF-scavenging capability, which, along with PF5 stabilization, results in enhanced rate capability of commercial LiNi0.6Mn0.2Co0.2O2 (NCM622)/graphite full cells, posing a significant potential for high-energy-density LIBs with long cycle stability. ko
dc.language 영어 ko
dc.publisher AMER CHEMICAL SOC ko
dc.title Dual-Functional Electrolyte Additives toward Long-Cycling Lithium-Ion Batteries : Ecofriendly Designed Carbonate Derivatives ko
dc.type ARTICLE ko
dc.identifier.scopusid 2-s2.0-85085531382 ko
dc.identifier.wosid 000537731900086 ko
dc.type.rims ART ko
dc.identifier.doi 10.1021/acsami.0c04372 ko
dc.identifier.url https://pubs.acs.org/doi/10.1021/acsami.0c04372 ko
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