There are no files associated with this item.
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 9469 | - |
dc.citation.number | 24 | - |
dc.citation.startPage | 9460 | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 59 | - |
dc.contributor.author | Kumar, Amit | - |
dc.contributor.author | Kumari, Nitee | - |
dc.contributor.author | Dubbu, Sateesh | - |
dc.contributor.author | Kumar, Sumit | - |
dc.contributor.author | Kwon, Taewan | - |
dc.contributor.author | Koo, Jung Hun | - |
dc.contributor.author | Lim, Jongwon | - |
dc.contributor.author | Kim, Inki | - |
dc.contributor.author | Cho, Yoon-Kyoung | - |
dc.contributor.author | Rho, Junsuk | - |
dc.contributor.author | Lee, In Su | - |
dc.date.accessioned | 2023-12-21T17:36:45Z | - |
dc.date.available | 2023-12-21T17:36:45Z | - |
dc.date.created | 2020-05-19 | - |
dc.date.issued | 2020-06 | - |
dc.description.abstract | Interest and challenges remain in designing and synthesizing catalysts with nature-like complexity at few-nm scale to harness unprecedented functionalities by using sustainable solar light. We introduce "nanocatalosomes"-a bio-inspired bilayer-vesicular design of nanoreactor with metallic bilayer shell-in-shell structure, having numerous controllable confined cavities within few-nm interlayer space, customizable with different noble metals. The intershell-confined plasmonically coupled hot-nanospaces within the few-nm cavities play a pivotal role in harnessing catalytic effects for various organic transformations, as demonstrated by "acceptorless dehydrogenation", "Suzuki-Miyaura cross-coupling" and "alkynyl annulation" affording clean conversions and turnover frequencies (TOFs) at least one order of magnitude higher than state-of-the-art Au-nanorod-based plasmonic catalysts. This work paves the way towards next-generation nanoreactors for chemical transformations with solar energy. | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.59, no.24, pp.9460 - 9469 | - |
dc.identifier.doi | 10.1002/anie.202001531 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.scopusid | 2-s2.0-85084010790 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/32149 | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202001531 | - |
dc.identifier.wosid | 000529657900001 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Nanocatalosomes as Plasmonic Bilayer Shells with Interlayer Catalytic Nanospaces for Solar-Light-Induced Reactions | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article; Early Access | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | bilayer structures | - |
dc.subject.keywordAuthor | nanocatalysts | - |
dc.subject.keywordAuthor | plasmonic-catalytic materials | - |
dc.subject.keywordAuthor | solar light | - |
dc.subject.keywordAuthor | Suzuki-Miyaura cross-coupling | - |
dc.subject.keywordPlus | HOTSPOTS | - |
dc.subject.keywordPlus | METAL NANOPARTICLES | - |
dc.subject.keywordPlus | HOT-CARRIER | - |
dc.subject.keywordPlus | GOLD | - |
dc.subject.keywordPlus | NANOCAGES | - |
dc.subject.keywordPlus | OXYGEN | - |
dc.subject.keywordPlus | COLLOIDOSOMES | - |
dc.subject.keywordPlus | NANOSHELLS | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.subject.keywordPlus | CHEMISTRY | - |
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Tel : 052-217-1404 / Email : scholarworks@unist.ac.kr
Copyright (c) 2023 by UNIST LIBRARY. All rights reserved.
ScholarWorks@UNIST was established as an OAK Project for the National Library of Korea.