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DC Field | Value | Language |
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dc.citation.endPage | 14895 | - |
dc.citation.number | 35 | - |
dc.citation.startPage | 14891 | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 59 | - |
dc.contributor.author | Pati, Palas Baran | - |
dc.contributor.author | Jin, Eunji | - |
dc.contributor.author | Kim, Yohan | - |
dc.contributor.author | Kim, Yongchul | - |
dc.contributor.author | Mun, Jinhong | - |
dc.contributor.author | Kim, So Jung | - |
dc.contributor.author | Kang, Seok Ju | - |
dc.contributor.author | Choe, Wonyoung | - |
dc.contributor.author | Lee, Geunsik | - |
dc.contributor.author | Shin, Hyung-Joon | - |
dc.contributor.author | Park, Young S. | - |
dc.date.accessioned | 2023-12-21T17:11:50Z | - |
dc.date.available | 2023-12-21T17:11:50Z | - |
dc.date.created | 2020-05-11 | - |
dc.date.issued | 2020-08 | - |
dc.description.abstract | Polycyclic aromatic hydrocarbons (PAHs) are key components of organic electronics. The electronic properties of these carbon-rich materials can be controlled through doping with heteroatoms such as B and N, however, few convenient syntheses of BN-doped PAHs have been reported. Described herein is the rationally designed, two-step syntheses of previously unknown ixene and BN-doped ixene (B2N2-ixene), and their characterizations. Compared to ixene, B2N2-ixene absorbs longer-wavelength light and has a smaller electrochemical energy gap. In addition to its single-crystal structure, scanning tunneling microscopy revealed that B2N2-ixene adopts a nonplanar geometry on a Au(111) surface. The experimentally obtained electronic structure of B2N2-ixene and the effect of BN-doping were confirmed by DFT calculations. This synthesis enables the efficient and convenient construction of BN-doped systems with extended pi-conjugation that can be used in versatile organic electronics applications. | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.59, no.35, pp.14891 - 14895 | - |
dc.identifier.doi | 10.1002/anie.202004049 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.scopusid | 2-s2.0-85086158284 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/32064 | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202004049 | - |
dc.identifier.wosid | 000538797100001 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Unveiling 79-year-old ixene and its BN-doped derivative | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | arylation | - |
dc.subject.keywordAuthor | doping | - |
dc.subject.keywordAuthor | isoelectronic analogues | - |
dc.subject.keywordAuthor | polycycles | - |
dc.subject.keywordAuthor | structure elucidation | - |
dc.subject.keywordPlus | OPTOELECTRONIC PROPERTIES | - |
dc.subject.keywordPlus | HETEROAROMATIC-COMPOUNDS | - |
dc.subject.keywordPlus | NANOGRAPHENE | - |
dc.subject.keywordPlus | BENZANNULATION | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | BORAZINE | - |
dc.subject.keywordPlus | ANALOGS | - |
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