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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 14776 | - |
dc.citation.number | 44 | - |
dc.citation.startPage | 14773 | - |
dc.citation.title | CHEMISTRY-A EUROPEAN JOURNAL | - |
dc.citation.volume | 19 | - |
dc.contributor.author | Moerdyk, Jonathan P. | - |
dc.contributor.author | Bielawski, Christopher W. | - |
dc.date.accessioned | 2023-12-22T03:16:31Z | - |
dc.date.available | 2023-12-22T03:16:31Z | - |
dc.date.created | 2020-03-04 | - |
dc.date.issued | 2013-10 | - |
dc.description.abstract | C-H bound: Diamidocarbenes were found to facilitate highly selective CH bond activation in hydrocarbons containing benzylic, allylic, or α‐carbonyl positions. Mechanistic studies showed a preference for intramolecular CH insertion for CH bonds at more substituted carbon atoms, whereas intermolecular insertions were enabled by relatively electron‐deficient substrates. The diamidocarbenes also promoted metal‐ and additive‐free transfer hydrogenations. | - |
dc.identifier.bibliographicCitation | CHEMISTRY-A EUROPEAN JOURNAL, v.19, no.44, pp.14773 - 14776 | - |
dc.identifier.doi | 10.1002/chem.201302691 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.scopusid | 2-s2.0-84885864710 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/31479 | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201302691 | - |
dc.identifier.wosid | 000331300600003 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | N,N '-Diamidocarbenes Facilitate Selective C-H Insertions and Transfer Hydrogenations | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | carbenes | - |
dc.subject.keywordAuthor | C-H activation | - |
dc.subject.keywordAuthor | dehydrogenation | - |
dc.subject.keywordAuthor | diamidocarbene | - |
dc.subject.keywordAuthor | transfer hydrogenation | - |
dc.subject.keywordPlus | N-HETEROCYCLIC CARBENE | - |
dc.subject.keywordPlus | FUNCTIONALIZATION/COPE REARRANGEMENT | - |
dc.subject.keywordPlus | CATALYTIC FUNCTIONALIZATION | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.subject.keywordPlus | BONDS | - |
dc.subject.keywordPlus | CYCLOADDITION | - |
dc.subject.keywordPlus | VERSATILE | - |
dc.subject.keywordPlus | BACKBONE | - |
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