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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 497 | - |
dc.citation.number | 3 | - |
dc.citation.startPage | 493 | - |
dc.citation.title | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | - |
dc.citation.volume | 2014 | - |
dc.contributor.author | Arumugam, Kuppuswamy | - |
dc.contributor.author | Varghese, Bibin | - |
dc.contributor.author | Brantley, Johnathan N. | - |
dc.contributor.author | Konda, Sai S. M. | - |
dc.contributor.author | Lynch, Vincent M. | - |
dc.contributor.author | Bielawski, Christopher W. | - |
dc.date.accessioned | 2023-12-22T03:07:40Z | - |
dc.date.available | 2023-12-22T03:07:40Z | - |
dc.date.created | 2020-03-04 | - |
dc.date.issued | 2014-01 | - |
dc.description.abstract | A series of N-heterocyclic carbene (NHC) supported gold(I) complexes were synthesized, characterized in solution as well as in the solid state, and examined as precatalysts for 1,6-enyne cycloisomerization reactions. The product mixtures obtained for a variety of 1,6-enyne isomerizations were governed primarily by the electronic properties of the aforementioned precatalysts. In particular, precatalysts containing electronic-rich NHC ligands showed increased selectivity for bicyclic products, whereas analogous precatalysts supported by electron-deficient NHCs preferentially afforded olefinic products. | - |
dc.identifier.bibliographicCitation | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, v.2014, no.3, pp.493 - 497 | - |
dc.identifier.doi | 10.1002/ejoc.201301137 | - |
dc.identifier.issn | 1434-193X | - |
dc.identifier.scopusid | 2-s2.0-84892619515 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/31471 | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201301137 | - |
dc.identifier.wosid | 000330801400002 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | 1,6-Enyne Cyclizations Catalyzed by N-Heterocyclic Carbene Supported Gold Complexes: Deconvoluting Sterics and Electronics | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | N-heterocyclic carbenes | - |
dc.subject.keywordAuthor | Gold | - |
dc.subject.keywordAuthor | Isomerization | - |
dc.subject.keywordAuthor | Enynes | - |
dc.subject.keywordAuthor | Steric hindrance | - |
dc.subject.keywordPlus | INTERMOLECULAR ADDITION | - |
dc.subject.keywordPlus | EFFICIENT | - |
dc.subject.keywordPlus | PLATINUM | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordPlus | CYCLOISOMERIZATIONS | - |
dc.subject.keywordPlus | HYDROXYCYCLIZATION | - |
dc.subject.keywordPlus | ALKOXYCYCLIZATION | - |
dc.subject.keywordPlus | HYDROAMINATION | - |
dc.subject.keywordPlus | HYDROARYLATION | - |
dc.subject.keywordPlus | REARRANGEMENT | - |
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