File Download

There are no files associated with this item.

  • Find it @ UNIST can give you direct access to the published full text of this article. (UNISTARs only)
Related Researcher

BielawskiChristopher W

Bielawski, Christopher W.
Read More

Views & Downloads

Detailed Information

Cited time in webofscience Cited time in scopus
Metadata Downloads

Full metadata record

DC Field Value Language
dc.citation.endPage 497 -
dc.citation.number 3 -
dc.citation.startPage 493 -
dc.citation.title EUROPEAN JOURNAL OF ORGANIC CHEMISTRY -
dc.citation.volume 2014 -
dc.contributor.author Arumugam, Kuppuswamy -
dc.contributor.author Varghese, Bibin -
dc.contributor.author Brantley, Johnathan N. -
dc.contributor.author Konda, Sai S. M. -
dc.contributor.author Lynch, Vincent M. -
dc.contributor.author Bielawski, Christopher W. -
dc.date.accessioned 2023-12-22T03:07:40Z -
dc.date.available 2023-12-22T03:07:40Z -
dc.date.created 2020-03-04 -
dc.date.issued 2014-01 -
dc.description.abstract A series of N-heterocyclic carbene (NHC) supported gold(I) complexes were synthesized, characterized in solution as well as in the solid state, and examined as precatalysts for 1,6-enyne cycloisomerization reactions. The product mixtures obtained for a variety of 1,6-enyne isomerizations were governed primarily by the electronic properties of the aforementioned precatalysts. In particular, precatalysts containing electronic-rich NHC ligands showed increased selectivity for bicyclic products, whereas analogous precatalysts supported by electron-deficient NHCs preferentially afforded olefinic products. -
dc.identifier.bibliographicCitation EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, v.2014, no.3, pp.493 - 497 -
dc.identifier.doi 10.1002/ejoc.201301137 -
dc.identifier.issn 1434-193X -
dc.identifier.scopusid 2-s2.0-84892619515 -
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/31471 -
dc.identifier.url https://onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201301137 -
dc.identifier.wosid 000330801400002 -
dc.language 영어 -
dc.publisher WILEY-V C H VERLAG GMBH -
dc.title 1,6-Enyne Cyclizations Catalyzed by N-Heterocyclic Carbene Supported Gold Complexes: Deconvoluting Sterics and Electronics -
dc.type Article -
dc.description.isOpenAccess FALSE -
dc.relation.journalWebOfScienceCategory Chemistry, Organic -
dc.relation.journalResearchArea Chemistry -
dc.type.docType Article -
dc.description.journalRegisteredClass scie -
dc.description.journalRegisteredClass scopus -
dc.subject.keywordAuthor N-heterocyclic carbenes -
dc.subject.keywordAuthor Gold -
dc.subject.keywordAuthor Isomerization -
dc.subject.keywordAuthor Enynes -
dc.subject.keywordAuthor Steric hindrance -
dc.subject.keywordPlus INTERMOLECULAR ADDITION -
dc.subject.keywordPlus EFFICIENT -
dc.subject.keywordPlus PLATINUM -
dc.subject.keywordPlus LIGANDS -
dc.subject.keywordPlus CYCLOISOMERIZATIONS -
dc.subject.keywordPlus HYDROXYCYCLIZATION -
dc.subject.keywordPlus ALKOXYCYCLIZATION -
dc.subject.keywordPlus HYDROAMINATION -
dc.subject.keywordPlus HYDROARYLATION -
dc.subject.keywordPlus REARRANGEMENT -

qrcode

Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.