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DC Field | Value | Language |
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dc.citation.endPage | 12140 | - |
dc.citation.number | 23 | - |
dc.citation.startPage | 12133 | - |
dc.citation.title | INORGANIC CHEMISTRY | - |
dc.citation.volume | 50 | - |
dc.contributor.author | Jeong, Seok | - |
dc.contributor.author | Song, Xiaokai | - |
dc.contributor.author | Jeong, Sehyun | - |
dc.contributor.author | Oh, Minhak | - |
dc.contributor.author | Liu, Xinfang | - |
dc.contributor.author | Kim, Dongwook | - |
dc.contributor.author | Moon, Dohyun | - |
dc.contributor.author | Lah, Myoung Soo | - |
dc.date.accessioned | 2023-12-22T05:40:07Z | - |
dc.date.available | 2023-12-22T05:40:07Z | - |
dc.date.created | 2013-06-12 | - |
dc.date.issued | 2011-12 | - |
dc.description.abstract | Solvotherrnal reactions of manganese(II) chloride tetrahydrate with a bis-tetrazole ligand, 2,6-di( 1H-tetrazol-5-yl)naphthalene (H2NDT), in N,N'-dimethylforrnamide (DMF)/MeOH mixed solvent at two slightly different temperatures, 75 and 100 degrees C, led to two different metal-organic frameworks (MOFs), [(Mn3O)-O-II(HNDT)(2)(NDT)(DMF)(3)] (1) and [(Mn5O2)-O-II(HNDT)(2)(NDT)(2)(DMF)(8)] (2), with different net topologies. Single-crystal X-ray diffraction studies reveal that 1 is constructed from an unprecedented trinuclear building block, [(Mn3O)-O-II(CN4)(6)], as a 6-connected trigonal prismatic secondary building unit (SBU) of topological D-3h site symmetry, and that the ligand in the HNDT-1/NDT2- deprotonation states is a linker, where two tetrazole (CN4) groups of the ligand are connected via a rigid naphthyl group. The tetrazole groups in 1 adopt a 1,2-mu-bridging mode with the manganese(111) ions to form a mu(3)-oxo trinuclear SBU. The trigonal prismatic SBU in 1 is connected to six neighboring SBUs to form a three-dimensional MOF of acs net topology. 2 is constructed from an unprecedented pentanuclear building block, [MnII5O2(CN4)(8)], as an 8-connected tetragonal prismatic SBU of topological D-4h site symmetry. The tetrazole groups in 2 adopt monodentate, 1,2-mu- and 2,3-mu-bridging bidentate and 1,2,3-mu-bridging tridentate binding modes with the manganese(II) centers to form a bis-mu(3)-oxo pentanuclear SBU of local C-2 site symmetry. The tetragonal prismatic SBU in 2 is connected to eight neighboring SBUs to form a 3-D MOF of bcu net topology. | - |
dc.identifier.bibliographicCitation | INORGANIC CHEMISTRY, v.50, no.23, pp.12133 - 12140 | - |
dc.identifier.doi | 10.1021/ic201883f | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.scopusid | 2-s2.0-82355164587 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/3115 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=82355164587 | - |
dc.identifier.wosid | 000297274600036 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Metal-Organic Frameworks Based on Unprecedented Trinuclear and Pentanuclear Metal-Tetrazole Clusters as Secondary Building Units | - |
dc.type | Article | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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