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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 5809 | - |
dc.citation.number | 31 | - |
dc.citation.startPage | 5804 | - |
dc.citation.title | SOFT MATTER | - |
dc.citation.volume | 10 | - |
dc.contributor.author | Park, Soyoung | - |
dc.contributor.author | Ryu, Mi-Hee | - |
dc.contributor.author | Shin, Tae Joo | - |
dc.contributor.author | Cho, Byoung-Ki | - |
dc.date.accessioned | 2023-12-22T01:45:55Z | - |
dc.date.available | 2023-12-22T01:45:55Z | - |
dc.date.created | 2020-01-23 | - |
dc.date.issued | 2014-20 | - |
dc.description.abstract | In this paper, we report a C-3-symmetric liquid crystal (LC) with sixfold alkyl peripheries exhibiting an unusual smectic E-like organization in the LC state. Based on conformational considerations, the smectic assembly is attributed to the formation of an endo-type Y conformer of asymmetric triazolyl and benzylic groups that cannot be accessed in other C-3-symmetric molecules exclusively showing columnar assemblies. The Y conformers form a two-dimensional oblique lattice in the aromatic layers of the ordered smectic phase. In addition, the Y-shaped molecule in the smectic phases can change into a circular shape by the 1 : 1 hydrogen-bonding interaction with a gallic acid derivative, which leads to a hexagonal columnar LC phase. The triazole-based LC design concept proves the smectic LC assembly in the C-3-symmetric system, and provides the supramolecular manipulation of LC morphologies. | - |
dc.identifier.bibliographicCitation | SOFT MATTER, v.10, no.31, pp.5804 - 5809 | - |
dc.identifier.doi | 10.1039/c4sm00919c | - |
dc.identifier.issn | 1744-683X | - |
dc.identifier.scopusid | 2-s2.0-84904430496 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/30860 | - |
dc.identifier.url | https://pubs.rsc.org/en/content/articlelanding/2014/SM/C4SM00919C#!divAbstract | - |
dc.identifier.wosid | 000340428700017 | - |
dc.language | 영어 | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Smectic assemblies in C-3-symmetric hexa-alkylated liquid crystals: transformation from smectogen to discogen via hydrogen bonding | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical; Materials Science, Multidisciplinary; Physics, Multidisciplinary; Polymer Science | - |
dc.relation.journalResearchArea | Chemistry; Materials Science; Physics; Polymer Science | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | COLUMNAR MESOPHASES | - |
dc.subject.keywordPlus | MESOMORPHIC COMPLEXES | - |
dc.subject.keywordPlus | SHAPED MESOGENS | - |
dc.subject.keywordPlus | E-PHASE | - |
dc.subject.keywordPlus | 1,3,5-TRIAZINES | - |
dc.subject.keywordPlus | SEGREGATION | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | LIBRARIES | - |
dc.subject.keywordPlus | LAMELLAR | - |
dc.subject.keywordPlus | ACIDS | - |
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