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DC Field | Value | Language |
---|---|---|
dc.citation.number | 2 | - |
dc.citation.title | APPLIED ORGANOMETALLIC CHEMISTRY | - |
dc.citation.volume | 34 | - |
dc.contributor.author | Das Adhikary, Sirsendu | - |
dc.contributor.author | Mondal, Ambarish | - |
dc.contributor.author | Kisan, Hemanta K. | - |
dc.contributor.author | Bielawski, Christopher W. | - |
dc.contributor.author | Dinda, Joydev | - |
dc.date.accessioned | 2023-12-21T18:07:26Z | - |
dc.date.available | 2023-12-21T18:07:26Z | - |
dc.date.created | 2020-01-23 | - |
dc.date.issued | 2020-02 | - |
dc.description.abstract | A series of silver(I) and gold(I) carbene complexes of the type [M(L)(2,2 '-bipyridine)][PF6] (L = 1-benzyl-3-(2-pyridylmethyl)benzimidazolylidene; M = Ag (1); M = Au (3)) and [M(L)(carbazole)] (M = Ag (2); M = Au (4)) were synthesized and analyzed using a range of spectroscopic and crystallographic techniques. Inspection of the solid-state structures of 1, 2 and 4 revealed a number of intermolecular noncovalent interactions. In the solid-state structure adopted by 1, pi-pi and Ag-Ag interactions directed the complexes to orient in a head-to-tail fashion. The photophysical properties were found to be influenced by the ancillary ligands in solution as well as in the solid-state. Calculations were performed to support the aforementioned structural and optoelectronic assignments. | - |
dc.identifier.bibliographicCitation | APPLIED ORGANOMETALLIC CHEMISTRY, v.34, no.2 | - |
dc.identifier.doi | 10.1002/aoc.5335 | - |
dc.identifier.issn | 0268-2605 | - |
dc.identifier.scopusid | 2-s2.0-85076742977 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/30856 | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/full/10.1002/aoc.5335 | - |
dc.identifier.wosid | 000503564100001 | - |
dc.language | 영어 | - |
dc.publisher | WILEY | - |
dc.title | Bipyridyl/carbazolate silver(I) and gold(I) N-heterocyclic carbene complexes: A systematic study of geometric constraints and electronic properties | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Applied; Chemistry, Inorganic & Nuclear | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article; Early Access | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | N-heterocyclic carbene | - |
dc.subject.keywordAuthor | gold(I)-NHC | - |
dc.subject.keywordAuthor | silver(I)-NHC | - |
dc.subject.keywordAuthor | photoluminescent | - |
dc.subject.keywordAuthor | carbazole | - |
dc.subject.keywordPlus | BASIS-SETS | - |
dc.subject.keywordPlus | NHC | - |
dc.subject.keywordPlus | AG(I) | - |
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