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Bielawski, Christopher W.
Synthetic Materials & Macromolecules
Research Interests
  • Synthetic chemistry, materials science, polymer chemistry, catalysis, carbon-based materials


Atomic engineering of metastable BeO6 octahedra in a rocksalt framework

DC Field Value Language Lee, Woo Chul ko Kim, Sangtae ko Larsen, Eric S. ko Choi, Jung-Hae ko Baek, Seung-Hyub ko Lee, Minji ko Cho, Deok-Yong ko Lee, Han-Koo ko Hwang, Cheol Seong ko Bielawski, Christopher W. ko Kim, Seong Keun ko 2020-01-28T09:44:52Z - 2020-01-23 ko 2020-01 ko
dc.identifier.citation APPLIED SURFACE SCIENCE, v.501, pp.144280 ko
dc.identifier.issn 0169-4332 ko
dc.identifier.uri -
dc.description.abstract An atomic structure is widely recognized as the key that determines the physical properties of a material. A critical challenge to engineer the atomic structure is that many useful crystals are metastable under ambient conditions and difficult to realize. Here, it is demonstrated that highly metastable atomic arrangements can be synthesized in the isostructural matrix via atomic layer deposition. Studying highly metastable BeO6 octahedra in rocksalt MgO as a model system, it is experimentally and theoretically shown that the single-phase BexMg1-xO thin films adopt rocksalt structure over wurtzite for the composition range x < 0.21. The single-phase rocksalt films exhibit almost doubled dielectric constants with the presence of BeO6 octahedra. Such atomic environment engineering may create intriguing properties that have not been realized in the constituent materials. This work provides excellent opportunities to explore unprecedented materials properties via engineering metastable atomic arrangements using the isostructural matrix approach. ko
dc.language 영어 ko
dc.publisher ELSEVIER ko
dc.title Atomic engineering of metastable BeO6 octahedra in a rocksalt framework ko
dc.type ARTICLE ko
dc.identifier.scopusid 2-s2.0-85073189396 ko
dc.identifier.wosid 000504658100007 ko
dc.type.rims ART ko
dc.identifier.doi 10.1016/j.apsusc.2019.144280 ko
dc.identifier.url ko
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