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DC Field | Value | Language |
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dc.citation.startPage | 127478 | - |
dc.citation.title | JOURNAL OF MOLECULAR STRUCTURE | - |
dc.citation.volume | 1204 | - |
dc.contributor.author | Lee, Hyun-Jong | - |
dc.contributor.author | Jung, Seonho | - |
dc.contributor.author | Cha, Ji-Hyun | - |
dc.contributor.author | Nam, Dongsik | - |
dc.contributor.author | Choe, Wonyoung | - |
dc.contributor.author | Jung, Duk-Young | - |
dc.date.accessioned | 2023-12-21T17:51:27Z | - |
dc.date.available | 2023-12-21T17:51:27Z | - |
dc.date.created | 2020-01-06 | - |
dc.date.issued | 2020-03 | - |
dc.description.abstract | The heterometallic Cu–In complex salt [Cu(III) (dtc)2][In(III)I4](1) (dtc = S2CNEt2, diethyldithiocarbamate) was prepared by reactions of Cu(II) (dtc)2 and In(III)I3 in benzene solution. As a redox reaction, Cu(II) (dtc)2 was oxidized to [Cu(III) (dtc)2]+, and In(III)I3 was changed to [In(III)I4]−. The square−planar Cu(III)S4 local symmetry of 1 involves a distorted octahedral coordination environment via long−range intermolecular interactions and represents a new one-dimensional structure of [Cu(III) (dtc)2]+ units. The crystal packing system of 1 consists of many [Cu(III) (dtc)2]+ chains surrounded by six parallel chains without solvent molecules. The infrared spectra of 1 showed a higher-frequency C–N thioureide bond in Cu(III) (dtc)2 than that of pristine Cu(II) (dtc)2, which has a lower oxidation state due to the Cu(II) center. | - |
dc.identifier.bibliographicCitation | JOURNAL OF MOLECULAR STRUCTURE, v.1204, pp.127478 | - |
dc.identifier.doi | 10.1016/j.molstruc.2019.127478 | - |
dc.identifier.issn | 0022-2860 | - |
dc.identifier.scopusid | 2-s2.0-85076216485 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/30781 | - |
dc.identifier.url | https://www.sciencedirect.com/science/article/pii/S002228601931587X | - |
dc.identifier.wosid | 000508216300086 | - |
dc.language | 영어 | - |
dc.publisher | Elsevier BV | - |
dc.title | Trivalent copper and indium heterometallic complex with dithiocarbamate and iodide ligands | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | Copper | - |
dc.subject.keywordAuthor | Trivalent | - |
dc.subject.keywordAuthor | Indium | - |
dc.subject.keywordAuthor | Dithiocarbamate | - |
dc.subject.keywordAuthor | Iodide | - |
dc.subject.keywordAuthor | Heterometallic | - |
dc.subject.keywordPlus | THIN-FILMS | - |
dc.subject.keywordPlus | SOLAR-CELLS | - |
dc.subject.keywordPlus | MOLECULAR-STRUCTURE | - |
dc.subject.keywordPlus | CRYSTAL | - |
dc.subject.keywordPlus | PRECURSORS | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | CU | - |
dc.subject.keywordPlus | NANOCRYSTALS | - |
dc.subject.keywordPlus | EFFICIENCY | - |
dc.subject.keywordPlus | CUINSE2 | - |
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