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Kim, Guntae
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Research Interests
  • Solid Oxide Fuel Cells (SOFCs)& SOE, PEMFC, metal-air batteries, Metal-CO2 system, Catalyst for DRM

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Advanced Electrochemical Properties of PrBa0.5Sr0.5Co1.9Ni0.1O5+δ as a Bifunctional Catalyst for Rechargeable Zinc-Air Batteries

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dc.contributor.author Lee, Hansol ko
dc.contributor.author Gwon, Ohhun ko
dc.contributor.author Lim, Chaehyun ko
dc.contributor.author Kim, Jeongwon ko
dc.contributor.author Galindev, Oyunbileg ko
dc.contributor.author Kim, Guntae ko
dc.date.available 2019-12-20T00:31:44Z -
dc.date.created 2019-07-18 ko
dc.date.issued 2019-06 ko
dc.identifier.citation CHEMELECTROCHEM, v.6, no.12, pp.3154 - 3159 ko
dc.identifier.issn 2196-0216 ko
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/30626 -
dc.description.abstract Various simple and layered perovskites have been extensively investigated as promising cathode materials for metal-air batteries and fuel cells, because of their tunable structural, electronic, and chemical properties. However, the electrocatalytic activity of perovskite oxides towards the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) must be improved by increasing the slow kinetics and by decreasing the overpotential associated with those reactions. Doping with other transition metals such as Ni, Mn, Fe and Cu represents one of the effective chemical methods to improve the catalytic activity of perovskite oxides. Herein, we investigate Ni-doped cobalt-based double perovskites, PrBa0.5Sr0.5Co2-xNixO5+δ (x=0, 0.1, 0.2 and 0.3), as promising cathode materials for rechargeable alkaline Zn-air batteries. PrBa0.5Sr0.5Co1.9Ni0.1O5+δ (PBSCN1) shows low Tafel slopes (OER: 83 mV dec−1 and ORR: 67 mV dec−1), favorable onset potentials (OER: 1.513 V vs. RHE at 1 mA cm−2 and ORR: 0.720 V vs. RHE at −1 mA cm−2), and high limiting currents (OER: 25.20 mA cm−2 and ORR: −5.67 mA cm−2). In addition, it shows improved discharge-charge performances for a full-cell Zn-air battery. The enhanced electrochemical properties of PBSCN1 could be achieved by the high concentration of surface oxygen species, and the coexistence of different chemical states of cobalt cations caused by the presence of nickel cations in the lattice. Based on these results, PrBa0.5Sr0.5Co1.9Ni0.1O5+δ could be considered a promising cathode material for Zn-air battery systems. ko
dc.language 영어 ko
dc.publisher Wiley-VCH Verlag ko
dc.title Advanced Electrochemical Properties of PrBa0.5Sr0.5Co1.9Ni0.1O5+δ as a Bifunctional Catalyst for Rechargeable Zinc-Air Batteries ko
dc.type ARTICLE ko
dc.identifier.scopusid 2-s2.0-85068047743 ko
dc.identifier.wosid 000475465600025 ko
dc.type.rims ART ko
dc.identifier.doi 10.1002/celc.201900633 ko
dc.identifier.url https://onlinelibrary.wiley.com/doi/full/10.1002/celc.201900633 ko
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