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DC Field | Value | Language |
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dc.citation.endPage | 693 | - |
dc.citation.startPage | 686 | - |
dc.citation.title | CHEMICAL ENGINEERING JOURNAL | - |
dc.citation.volume | 369 | - |
dc.contributor.author | Lim, Jiyeon | - |
dc.contributor.author | Choi, Wonjung | - |
dc.contributor.author | Mok, Junghoon | - |
dc.contributor.author | Seo, Yongwon | - |
dc.date.accessioned | 2023-12-21T18:54:46Z | - |
dc.date.available | 2023-12-21T18:54:46Z | - |
dc.date.created | 2019-04-09 | - |
dc.date.issued | 2019-08 | - |
dc.description.abstract | Upgrading CO 2 -rich natural gas or biogas through CO 2 capture is essential to reduce greenhouse gas emissions and to increase its energy density. In this study, clathrate-based CO 2 capture from CO 2 -rich natural gas or biogas was investigated with a primary focus on kinetic CO 2 selectivity. The time-dependent CO 2 selectivity during clathrate formation for pure water, tetrahydrofuran (THF, 5.6 mol%) solution, and tetra-n-butylammonium chloride (TBAC, 3.3 mol%) solution was examined through direct composition analysis and in situ Raman spectroscopy. In pure water, the CO 2 composition in the clathrate phase was much higher at the early stage of clathrate formation than that at equilibrium, indicating that CO 2 is kinetically and thermodynamically selective. For both the THF (5.6 mol%) and TBAC (3.3 mol%) solutions, the CO 2 composition in the clathrate phase was almost constant during clathrate formation. However, the TBAC (3.3 mol%) solution showed significantly higher CO 2 composition (∼74%) throughout the reaction, whereas the THF (5.6 mol%) solution exhibited enrichment of CH 4 in the clathrate phase. The experimental results clearly demonstrate that CO 2 selectivity is dependent on both kinetics and equilibrium of clathrate hydrates and that the addition of thermodynamic promoters, such as THF and TBAC, can affect kinetic CO 2 selectivity as well as equilibrium CO 2 selectivity in the clathrate phase. | - |
dc.identifier.bibliographicCitation | CHEMICAL ENGINEERING JOURNAL, v.369, pp.686 - 693 | - |
dc.identifier.doi | 10.1016/j.cej.2019.03.117 | - |
dc.identifier.issn | 1385-8947 | - |
dc.identifier.scopusid | 2-s2.0-85062893668 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/30386 | - |
dc.identifier.url | https://www.sciencedirect.com/science/article/pii/S1385894719305820?via%3Dihub | - |
dc.identifier.wosid | 000463344800067 | - |
dc.language | 영어 | - |
dc.publisher | Elsevier B.V. | - |
dc.title | Kinetic CO 2 selectivity in clathrate-based CO 2 capture for upgrading CO 2 -rich natural gas and biogas | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Engineering, Environmental; Engineering, Chemical | - |
dc.relation.journalResearchArea | Engineering | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | Biogas | - |
dc.subject.keywordAuthor | Clathrate hydrates | - |
dc.subject.keywordAuthor | CO 2 | - |
dc.subject.keywordAuthor | Kinetic selectivity | - |
dc.subject.keywordAuthor | Natural gas | - |
dc.subject.keywordPlus | STORAGE | - |
dc.subject.keywordPlus | RECOVERY | - |
dc.subject.keywordPlus | CARBON-DIOXIDE CAPTURE | - |
dc.subject.keywordPlus | PRE-COMBUSTION CAPTURE | - |
dc.subject.keywordPlus | HYDRATE FORMATION | - |
dc.subject.keywordPlus | FLUE-GAS | - |
dc.subject.keywordPlus | SIMULATED BIOGAS | - |
dc.subject.keywordPlus | FUEL GAS | - |
dc.subject.keywordPlus | SEPARATION | - |
dc.subject.keywordPlus | METHANE | - |
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