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DC Field | Value | Language |
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dc.citation.endPage | 20182 | - |
dc.citation.number | 22 | - |
dc.citation.startPage | 20174 | - |
dc.citation.title | ACS APPLIED MATERIALS & INTERFACES | - |
dc.citation.volume | 11 | - |
dc.contributor.author | Shang, Xiaobo | - |
dc.contributor.author | Song, Inho | - |
dc.contributor.author | Lee, Jeong Hyeon | - |
dc.contributor.author | Choi, Wanuk | - |
dc.contributor.author | Ohtsu, Hiroyoshi | - |
dc.contributor.author | Jung, Gwan Yeong | - |
dc.contributor.author | Ahn, Jaeyong | - |
dc.contributor.author | Han, Myeonggeun | - |
dc.contributor.author | Koo, Jin Young | - |
dc.contributor.author | Kawano, Masaki | - |
dc.contributor.author | Kwak, Sang Kyu | - |
dc.contributor.author | Oh, Joon Hak | - |
dc.date.accessioned | 2023-12-21T19:07:34Z | - |
dc.date.available | 2023-12-21T19:07:34Z | - |
dc.date.created | 2019-06-25 | - |
dc.date.issued | 2019-06 | - |
dc.description.abstract | Chiral self-sorting has great potential for constructing new complex structures and determining chirality-dependent properties in multicomponent mixtures. However, it is still of great challenge to achieve high fidelity chiral self-discrimination. Besides, the researches on the coordination polymers or metal-organic frameworks for micro/nanooptoelectronics are still rare due to their low conductivity and difficulty in developing a rapid and simple scale-up synthetic method. Here, heterochiral supramolecular coordination networks (SCNs) were synthesized by the solvothermal reaction of naphthalene diimide enantiomers and cadmium iodide, using the chirality as a synthetic tuning parameter to control the morphologies. Intriguingly, heterochiral micro/nanocrystals exhibited photochromic and photodetecting properties. Furthermore, we also developed a simple and efficient doping method to enhance the conductivity and photoresponsivity of micro/nanocrystals using hydrazine. From experimental and theoretical studies, the mechanism was suggested as follows: the radicals in the singly occupied molecular orbital level of the ligands provide charge carriers that can undergo through-space transport between Ï€-πstacked ligands and the electron transfer from adsorbed hydrazine to the SCNs results in reduction of energy gap, leading to increased conductivity. Our findings demonstrate a simple and powerful strategy for implementing coordination networks with redox ligands for micro/nanooptoelectronic applications. | - |
dc.identifier.bibliographicCitation | ACS APPLIED MATERIALS & INTERFACES, v.11, no.22, pp.20174 - 20182 | - |
dc.identifier.doi | 10.1021/acsami.9b04653 | - |
dc.identifier.issn | 1944-8244 | - |
dc.identifier.scopusid | 2-s2.0-85066832398 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/27467 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/acsami.9b04653 | - |
dc.identifier.wosid | 000470938500056 | - |
dc.language | 영어 | - |
dc.publisher | American Chemical Society | - |
dc.title | Heterochiral Doped Supramolecular Coordination Networks for High-Performance Optoelectronics | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology; Materials Science, Multidisciplinary | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics; Materials Science | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | chiral self-discrimination | - |
dc.subject.keywordAuthor | doping | - |
dc.subject.keywordAuthor | micro/nanodevices | - |
dc.subject.keywordAuthor | optoelectronics | - |
dc.subject.keywordAuthor | supramolecular coordination network | - |
dc.subject.keywordPlus | Solvothermal reactions | - |
dc.subject.keywordPlus | Supramolecular coordination | - |
dc.subject.keywordPlus | Ligands | - |
dc.subject.keywordPlus | Hydrazine | - |
dc.subject.keywordPlus | Molecular orbitals | - |
dc.subject.keywordPlus | Naphthalene | - |
dc.subject.keywordPlus | Optoelectronic devices | - |
dc.subject.keywordPlus | Organic polymers | - |
dc.subject.keywordPlus | Organometallics | - |
dc.subject.keywordPlus | Supramolecular chemistry | - |
dc.subject.keywordPlus | Coordination networks | - |
dc.subject.keywordPlus | Metal organic framework | - |
dc.subject.keywordPlus | micro/nanodevices | - |
dc.subject.keywordPlus | Multicomponent mixture | - |
dc.subject.keywordPlus | Self discrimination | - |
dc.subject.keywordPlus | Cadmium compounds | - |
dc.subject.keywordPlus | Chirality | - |
dc.subject.keywordPlus | Crystalline materials | - |
dc.subject.keywordPlus | Doping (additives) | - |
dc.subject.keywordPlus | Free radical reactions | - |
dc.subject.keywordPlus | Singly occupied molecular orbitals | - |
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