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Rohde, Jan-Uwe
Transition Metal Chemistry
Research Interests
  • Inorganic chemistry, coordination chemistry, organometallic chemistry, chemical synthesis, catalysis, green chemistry, inorganic reaction mechanisms.

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Annulative π-Extension of Unactivated Benzene Derivatives through Nondirected C–H Arylation

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Title
Annulative π-Extension of Unactivated Benzene Derivatives through Nondirected C–H Arylation
Author
Lee, Jae BinJeon, Min HoSeo, Jeong Konvon Helden, GertRohde, Jan-UweZhao, Bum SukSeo, JongcheolHong, Sung You
Issue Date
2019-09
Publisher
American Chemical Society
Citation
ORGANIC LETTERS, v.21, no.17, pp.7004 - 7008
Abstract
Annulative π-extension chemistry provides a concise synthetic route to polycyclic arenes. Herein, we disclose a nondirected annulation approach of unactivated simple arenes. The palladium-catalyzed 2-fold C–H arylation event facilitates tandem C–C linkage relays to furnish fully benzenoid triphenylene frameworks using cyclic diaryliodonium salts. The inseparable regioisomeric mixture of 1- and 2-methyltriphenylenes is identified by the combined analysis of ion mobility-mass spectrometry, gas-phase infrared spectroscopy, and molecular simulation studies.
URI
https://scholarworks.unist.ac.kr/handle/201301/27369
URL
https://pubs.acs.org/doi/abs/10.1021/acs.orglett.9b02583
DOI
10.1021/acs.orglett.9b02583
ISSN
1523-7060
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CHM_Journal Papers
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