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Rohde, Jan-Uwe
Transition Metal Chemistry
Research Interests
  • Inorganic chemistry, coordination chemistry, organometallic chemistry, chemical synthesis, catalysis, green chemistry, inorganic reaction mechanisms.

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Organic Radical-Linked Covalent Triazine Framework with Paramagnetic Behavior

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dc.contributor.author Jiang, Yi ko
dc.contributor.author Oh, Inseon ko
dc.contributor.author Joo, Se Hun ko
dc.contributor.author Buyukcakir, Onur ko
dc.contributor.author Chen, Xiong ko
dc.contributor.author Lee, Sun Hwa ko
dc.contributor.author Huang, Ming ko
dc.contributor.author Seong, Won Kyung ko
dc.contributor.author Kim, Jin Hoon ko
dc.contributor.author Rohde, Jan-Uwe ko
dc.contributor.author Kwak, Sang Kyu ko
dc.contributor.author Yoo, Jung-Woo ko
dc.contributor.author Ruoff, Rodney S. ko
dc.date.available 2019-09-02T09:04:07Z -
dc.date.created 2019-06-20 ko
dc.date.issued 2019-05 ko
dc.identifier.citation ACS NANO, v.13, no.5, pp.5251 - 5258 ko
dc.identifier.issn 1936-0851 ko
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/27342 -
dc.description.abstract The production of multifunctional pure organic materials that combine different sizes of pores and a large number of electron spins is highly desirable due to their potential applications as polarizers for dynamic nuclear polarization nuclear magnetic resonance and as catalysts and magnetic separation media. Here, we report a polychlorotriphenylmethyl radical-linked covalent triazine framework (PTMR-CTF). Two different sizes of micropores were established by N-2 sorption and the presence of unpaired electrons (carbon radicals) by electron spin resonance and superconducting quantum interference device vibrating sample magnetometer analyses. Magnetization measurements demonstrate that this material exhibits spin-half paramagnetism with a spin concentration of similar to 2.63 X 10(23) spins/mol. We also determined the microscopic origin of the magnetic moments in PTMR-CTF by investigating its spin density and electronic structure using density functional theory calculations. ko
dc.language 영어 ko
dc.publisher AMER CHEMICAL SOC ko
dc.title Organic Radical-Linked Covalent Triazine Framework with Paramagnetic Behavior ko
dc.type ARTICLE ko
dc.identifier.scopusid 2-s2.0-85065794696 ko
dc.identifier.wosid 000469886300034 ko
dc.type.rims ART ko
dc.identifier.doi 10.1021/acsnano.8b09634 ko
dc.identifier.url https://pubs.acs.org/doi/10.1021/acsnano.8b09634 ko
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