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Joo, Sang Hoon
Nanomaterials & Catalysis Lab
Research Interests
  • Catalyst, energy conversion, fuel cells, electrolyzer, ORR, HER, OER

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In situ-generated metal oxide catalyst during CO oxidation reaction transformed from redox-active metal-organic framework-supported palladium nanoparticles

Cited 4 times inthomson ciCited 5 times inthomson ci
Title
In situ-generated metal oxide catalyst during CO oxidation reaction transformed from redox-active metal-organic framework-supported palladium nanoparticles
Author
Kim, Jin YeongJin, MingshiLee, Kyung JooCheon, Jae YeongJoo, Sang HoonKim, Ji ManMoon, Hoi Ri
Keywords
Active catalyst; Catalytically active species; Co oxidation; In-situ; Metal organic framework; Metal oxide catalysts; Metal oxides; Metal-organic; Nano-catalyst; Palladium nanoparticles; Redox-active; Room temperature; Supported Pd
Issue Date
2012-08
Publisher
SPRINGER
Citation
NANOSCALE RESEARCH LETTERS, v.7, no.1, pp.1 - 8
Abstract
The preparation of redox-active metal-organic framework (ra-MOF)-supported Pd nanoparticles (NPs) via the redox couple-driven method is reported, which can yield unprotected metallic NPs at room temperature within 10 min without the use of reducing agents. The Pd@ra-MOF has been exploited as a precursor of an active catalyst for CO oxidation. Under the CO oxidation reaction condition, Pd@ra-MOF is transformed into a PdOx-NiOy/C nanocomposite to generate catalytically active species in situ, and the resultant nanocatalyst shows sustainable activity through synergistic stabilization.
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DOI
10.1186/1556-276X-7-461
ISSN
1556-276X
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SNS_Journal Papers
ECHE_Journal Papers
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