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DC Field | Value | Language |
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dc.citation.endPage | 6751 | - |
dc.citation.number | 11 | - |
dc.citation.startPage | 6737 | - |
dc.citation.title | JOURNAL OF ORGANIC CHEMISTRY | - |
dc.citation.volume | 84 | - |
dc.contributor.author | Maiti, Saikat | - |
dc.contributor.author | Kim, Jaeshin | - |
dc.contributor.author | Park, Jae-Heon | - |
dc.contributor.author | Nam, Dongsik | - |
dc.contributor.author | Lee, Jae Bin | - |
dc.contributor.author | Kim, Ye Jin | - |
dc.contributor.author | Kee, Jung-Min | - |
dc.contributor.author | Seo, Jeong Kon | - |
dc.contributor.author | Myung, Kyungjae | - |
dc.contributor.author | Rohde, Jan-Uwe | - |
dc.contributor.author | Choe, Wonyoung | - |
dc.contributor.author | Kwon, Oh Hoon | - |
dc.contributor.author | Hong, Sung You | - |
dc.date.accessioned | 2023-12-21T19:08:04Z | - |
dc.date.available | 2023-12-21T19:08:04Z | - |
dc.date.created | 2019-05-05 | - |
dc.date.issued | 2019-06 | - |
dc.description.abstract | Herein, we report chemoselective trifluoroethylation routes of unmasked 2-arylquinazolin-4(3H)-ones using mesityl(2,2,2-trifluoroethyl)iodonium triflate at room temperature. Homologous C-, O-, and N-functionalized subclasses are accessed in a straightforward manner with a wide substrate scope. These chemoselective branching events are driven by Pd-catalyzed ortho-selective C–H activation at the pendant aryl ring and base-promoted reactivity modulation of the amide group, leveraging the intrinsic directing capability and competing pronucleophilicity of the quinazolin-4(3H)-one framework. Furthermore, outstanding photostability of the quinazolin-4(3H)-one family associated with nonradiative decay is presented. | - |
dc.identifier.bibliographicCitation | JOURNAL OF ORGANIC CHEMISTRY, v.84, no.11, pp.6737 - 6751 | - |
dc.identifier.doi | 10.1021/acs.joc.9b00470 | - |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.scopusid | 2-s2.0-85066127191 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/26874 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/acs.joc.9b00470 | - |
dc.identifier.wosid | 000471212000019 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Chemoselective Trifluoroethylation Reactions of Quinazolinones and Identification of Photostability | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | EXCITED-STATE DYNAMICS | - |
dc.subject.keywordPlus | LATE-STAGE FUNCTIONALIZATION | - |
dc.subject.keywordPlus | C-H TRIFLUOROETHYLATION | - |
dc.subject.keywordPlus | OXIDATIVE CYCLIZATION | - |
dc.subject.keywordPlus | DIARYLIODONIUM SALTS | - |
dc.subject.keywordPlus | PALLADIUM | - |
dc.subject.keywordPlus | QUINAZOLIN-4(3H)-ONES | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | FLUORINE | - |
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