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DC Field | Value | Language |
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dc.citation.endPage | 7300 | - |
dc.citation.number | 19 | - |
dc.citation.startPage | 7293 | - |
dc.citation.title | MACROMOLECULES | - |
dc.citation.volume | 35 | - |
dc.contributor.author | Jang, Sung-Yeon | - |
dc.contributor.author | Sotzing, Gregory A. | - |
dc.contributor.author | Marquez, Manuel | - |
dc.date.accessioned | 2023-12-22T11:36:57Z | - |
dc.date.available | 2023-12-22T11:36:57Z | - |
dc.date.created | 2019-05-16 | - |
dc.date.issued | 2002-09 | - |
dc.description.abstract | Herein we describe the preparation of intrinsically conducting poly(thiophene) via two different routes: solution- and solid-state cross-linking of terthiophene moieties. The solution-state crosslinking of terthiophene moieties was performed using conventional electrochemical polymerization in which insoluble cross-linked polymer was precipitated onto the electrode from electrolyte solution of the monomer by oxidative coupling of terthiophene units in the monomer, 5-norbornene-endo-2,3-bis(methylene-3'-[2,2':5',2"]-terthiophene acetate). In the alternative route, a precursor polymer, poly(norbornylene), prepared from the ring-opening metathesis polymerization (ROMP) of 5-norbornene-endo-2,3-bis(methylene-3'-[2,2':5',2"]-terthiophene acetate), was coated on either a conducting or insulating, surface, and then the terthiophene units were cross-linked to form intrinsically conductive polymer (ICP) via electrochemical and chemical oxidation, respectively. More highly.. conjugated ICP was observed by performing oxidative cross-linking of the polymer in the solid state, in contrast to the cross-linked intrinsically conducting polymer prepared via electrochemical polymerization of 5-norbornene-endo-2,3-bis(methylene-3'-[2,2':5',2"]-terthiophene acetate) from solution. Electrical conductivities for the polymers obtained via solid-state chemical oxidative cross-linking were on the order of 1 x 10(-3) S/cm. | - |
dc.identifier.bibliographicCitation | MACROMOLECULES, v.35, no.19, pp.7293 - 7300 | - |
dc.identifier.doi | 10.1021/ma0202484 | - |
dc.identifier.issn | 0024-9297 | - |
dc.identifier.scopusid | 2-s2.0-0037056331 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/26685 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/ma0202484 | - |
dc.identifier.wosid | 000177927200020 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Intrinsically conducting polymer networks of poly(thiophene) via solid-state oxidative cross-linking of a poly(norbornylene) containing terthiophene moieties | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Polymer Science | - |
dc.relation.journalResearchArea | Polymer Science | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | THIOPHENE | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | DEVICES | - |
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