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Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)
  • Crystal Engineering
  • Supramolecular coordination chemistry

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TiO2 Composites for Efficient Poly(3-thiophene acetic acid) Sensitized Solar Cells

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dc.contributor.author Cho, Younkyung ko
dc.contributor.author Kim, Hyunho ko
dc.contributor.author Oh, Minhak ko
dc.contributor.author Lah, Myoung Soo ko
dc.contributor.author Majima, Yutaka ko
dc.contributor.author Sohn, Kee-Sun ko
dc.contributor.author Pyo, Myoungho ko
dc.date.available 2014-04-09T08:28:57Z -
dc.date.created 2013-06-04 ko
dc.date.issued 2011-02 ko
dc.identifier.citation JOURNAL OF THE ELECTROCHEMICAL SOCIETY, v.158, no.2, pp.B106 - B111 ko
dc.identifier.issn 0013-4651 ko
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/2658 -
dc.description.abstract The effect of TiO2 mesoporous structures sensitized with poly (3-thiophene acetic acid) (PTAA) on the photovoltaic performance was investigated. In contrast to conventional Ru-complex dye-sensitized solar cells (DSCs), the cell efficiency(eta) of PTAA-sensitized solar cells exhibited strong dependence on the TiO2 pore structures. Incorporation of up to 40 wt % large TiO2 nanoparticles (L-TiO2) into small TiO2 nanoparticles (S-TiO2) increased eta, in spite of a reduction in dye loading due to a decrease in surface area. The highest eta of 2.36 +/- 0.04% was obtained for a TiO2 film comprised of S-TiO2 (60 wt %) and L-TiO2 (40 wt %). Electrochemical impedance measurements suggested that the 25% increase in eta for the DSC comprised of 40 wt % L-TiO2 resulted not from rapid diffusion of the redox electrolyte through the larger pores, but instead was due to the higher electron density in the conduction band of TiO2. It was inferred, therefore, that the highest eta obtained for the DSC comprised of 40 wt % L-TiO2 was due to the high degree of anchoring of COOH groups. This inference was further confirmed by obtaining an eta of 2.92 +/- 0.06%, the highest eta ever reported for a polymer-dye based DSC, using a low-molecular weight PTAA sensitizer. ko
dc.description.statementofresponsibility close -
dc.language 영어 ko
dc.publisher ELECTROCHEMICAL SOC INC ko
dc.title TiO2 Composites for Efficient Poly(3-thiophene acetic acid) Sensitized Solar Cells ko
dc.type ARTICLE ko
dc.identifier.scopusid 2-s2.0-78650744737 ko
dc.identifier.wosid 000285765600026 ko
dc.type.rims ART ko
dc.description.wostc 4 *
dc.description.scopustc 4 *
dc.date.tcdate 2015-02-28 *
dc.date.scptcdate 2014-08-27 *
dc.identifier.doi 10.1149/1.3519305 ko
dc.identifier.url http://jes.ecsdl.org/content/158/2/B106 ko
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