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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 764 | - |
dc.citation.number | 5 | - |
dc.citation.startPage | 759 | - |
dc.citation.title | ACS CATALYSIS | - |
dc.citation.volume | 2 | - |
dc.contributor.author | Kwon, Youngkook | - |
dc.contributor.author | Birdja, Yuvraj | - |
dc.contributor.author | Spanos, Ioannis | - |
dc.contributor.author | Rodriguez, Paramaconi | - |
dc.contributor.author | Koper, Marc T. M. | - |
dc.date.accessioned | 2023-12-22T05:09:02Z | - |
dc.date.available | 2023-12-22T05:09:02Z | - |
dc.date.created | 2019-04-17 | - |
dc.date.issued | 2012-05 | - |
dc.description.abstract | A carbon supported platinum electrode in a bismuth saturated solution at a carefully chosen potential is capable of oxidizing glycerol to dihydroxyacetone with 100% selectivity. In the absence of bismuth, the primary alcohol oxidation is dominant. Using a combination of online HPLC and in situ FTIR, it is shown that Bi blocks the pathway for primary oxidation but also provides a specific Pt-Bi surface site poised for secondary alcohol oxidation. | - |
dc.identifier.bibliographicCitation | ACS CATALYSIS, v.2, no.5, pp.759 - 764 | - |
dc.identifier.doi | 10.1021/cs200599g | - |
dc.identifier.issn | 2155-5435 | - |
dc.identifier.scopusid | 2-s2.0-84860704668 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/26543 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/cs200599g | - |
dc.identifier.wosid | 000303492400009 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Highly Selective Electro-Oxidation of Glycerol to Dihydroxyacetone on Platinum in the Presence of Bismuth | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | glycerol | - |
dc.subject.keywordAuthor | dihydroxyacetone | - |
dc.subject.keywordAuthor | bismuth | - |
dc.subject.keywordAuthor | platinum | - |
dc.subject.keywordAuthor | electrocatalysis | - |
dc.subject.keywordPlus | CATALYTIC-OXIDATION | - |
dc.subject.keywordPlus | FORMIC-ACID | - |
dc.subject.keywordPlus | BI | - |
dc.subject.keywordPlus | ELECTRODES | - |
dc.subject.keywordPlus | ADSORPTION | - |
dc.subject.keywordPlus | CONVERSION | - |
dc.subject.keywordPlus | MECHANISM | - |
dc.subject.keywordPlus | CHEMICALS | - |
dc.subject.keywordPlus | GOLD | - |
dc.subject.keywordPlus | AU | - |
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