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- Kwon, Youngkook
- Electrochemistry Lab for Energy and Environment
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Electro-Oxidation of Glycerol on Platinum Modified by Adatoms: Activity and Selectivity Effects
- Author(s)
- Kwon, Youngkook, Hersbach, Thomas J. P., Koper, Marc T. M.
- Issued Date
- 2014-09
- Citation
- TOPICS IN CATALYSIS, v.57, no.14-16, pp.1272 - 1276
- Abstract
- Antimony irreversibly adsorbed on a carbon supported platinum electrode oxidizes glycerol selectively to dihydroxyacetone with a lower onset potential (ca. 150 mV) and a higher peak current density (ca. 170 %) compared to clean Pt/C. Pb, In, and Sn also promote the catalytic activity of glycerol oxidation, however the reaction pathway towards the primary alcohol oxidation remains unchanged. Higher surface coverage by adatoms on Pt/C generally increases the activity of glycerol oxidation.
- Publisher
- SPRINGER/PLENUM PUBLISHERS
- ISSN
- 1022-5528
- Keyword (Author)
- Glycerol, Dihydroxyacetone, Antimony, Platinum, Electrocatalysis
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