Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 1456 | - |
dc.citation.number | 5 | - |
dc.citation.startPage | 1450 | - |
dc.citation.title | CHEMICAL SCIENCE | - |
dc.citation.volume | 10 | - |
dc.contributor.author | Zhang, Su-Yun | - |
dc.contributor.author | Kochovski, Zdravko | - |
dc.contributor.author | Lee, Hui-Chun | - |
dc.contributor.author | Lu, Yan | - |
dc.contributor.author | Zhang, Hemin | - |
dc.contributor.author | Zhang, Jie | - |
dc.contributor.author | Sun, Jian-Ke | - |
dc.contributor.author | Yuan, Jiayin | - |
dc.date.accessioned | 2023-12-21T19:38:17Z | - |
dc.date.available | 2023-12-21T19:38:17Z | - |
dc.date.created | 2019-02-19 | - |
dc.date.issued | 2019-02 | - |
dc.description.abstract | Exploration of metal clusters (MCs) adaptive to both aqueous and oil phases without disturbing their size is promising for a broad scope of applications. The state-of-the-art approach via ligandbinding may perturb MCs' size due to varied metal-ligand binding strength when shuttling between solvents of different polarity. Herein, we applied physical confinement of a series of small noble MCs (<1 nm) inside ionic organic cages (I-Cages), which by means of anion exchange enables reversible transfer of MCs between aqueous and hydrophobic solutions without varying their ultrasmall size. Moreover, the MCs@I-Cage hybrid serves as a recyclable, reaction-switchable catalyst featuring high activity in liquid-phase NH3BH3 (AB) hydrolysis reaction with a turnover frequency (TOF) of 115 min(-1). | - |
dc.identifier.bibliographicCitation | CHEMICAL SCIENCE, v.10, no.5, pp.1450 - 1456 | - |
dc.identifier.doi | 10.1039/c8sc04375b | - |
dc.identifier.issn | 2041-6520 | - |
dc.identifier.scopusid | 2-s2.0-85060861084 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/26446 | - |
dc.identifier.url | https://pubs.rsc.org/en/Content/ArticleLanding/2019/SC/C8SC04375B#!divAbstract | - |
dc.identifier.wosid | 000457448700019 | - |
dc.language | 영어 | - |
dc.publisher | Royal Society of Chemistry | - |
dc.title | Ionic organic cage-encapsulating phase-transferable metal clusters | - |
dc.type | Article | - |
dc.description.isOpenAccess | TRUE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | GOLD NANOPARTICLES | - |
dc.subject.keywordPlus | AMMONIA-BORANE | - |
dc.subject.keywordPlus | NANOCLUSTERS | - |
dc.subject.keywordPlus | WATER | - |
dc.subject.keywordPlus | CATALYSTS | - |
dc.subject.keywordPlus | DEHYDROGENATION | - |
dc.subject.keywordPlus | NETWORKS | - |
dc.subject.keywordPlus | ROUTE | - |
dc.subject.keywordPlus | AU | - |
dc.subject.keywordPlus | AG | - |
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