There are no files associated with this item.
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 4553 | - |
dc.citation.number | 11 | - |
dc.citation.startPage | 4547 | - |
dc.citation.title | NEW JOURNAL OF CHEMISTRY | - |
dc.citation.volume | 43 | - |
dc.contributor.author | Shahid, Mushtaq Ahmed | - |
dc.contributor.author | Shi, Genggongwo | - |
dc.contributor.author | Yousuf, Muhammad | - |
dc.contributor.author | Madridejos, Jenica Marie L. | - |
dc.contributor.author | Mahmood, Farzana | - |
dc.contributor.author | Rasheed, Lubna | - |
dc.date.accessioned | 2023-12-21T19:20:36Z | - |
dc.date.available | 2023-12-21T19:20:36Z | - |
dc.date.created | 2019-03-28 | - |
dc.date.issued | 2019-03 | - |
dc.description.abstract | A carbazole-based fluorescent probe was synthesized and found to fluoresce (lambda(em,max) = 440 nm) in the presence of hypochlorite. Guided by a series of control experiments and kinetics studies, protocols for using the sensor to measure the concentration of hypochlorite under a range of conditions were established. The synthesized probe is highly selective for hypochlorite in the presence of interfering strong oxidants including dichromates (Cr2O72-). The probe was also used to quantify the presence of the ClO- oxidant in various sources of water conveniently. The underlying mechanism of the sensor was elucidated by NMR, HRMS, and cyclic voltammetry and further confirmed by DFT calculations to proceed through a series of tandem proton and electron transfer processes. | - |
dc.identifier.bibliographicCitation | NEW JOURNAL OF CHEMISTRY, v.43, no.11, pp.4547 - 4553 | - |
dc.identifier.doi | 10.1039/c9nj00610a | - |
dc.identifier.issn | 1144-0546 | - |
dc.identifier.scopusid | 2-s2.0-85062890710 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/26409 | - |
dc.identifier.url | https://pubs.rsc.org/en/Content/ArticleLanding/2019/NJ/C9NJ00610A#!divAbstract | - |
dc.identifier.wosid | 000460972700027 | - |
dc.language | 영어 | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | A "turn-on" fluorescent probe for highly selective discrimination of hypochlorite (ClO-) from oxidants including dichromates (Cr2O72-) in aqueous media | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | LIVE-CELL | - |
dc.subject.keywordPlus | TAP WATER | - |
dc.subject.keywordPlus | BIOLOGICAL SAMPLES | - |
dc.subject.keywordPlus | RAPID DETECTION | - |
dc.subject.keywordPlus | RECENT PROGRESS | - |
dc.subject.keywordPlus | ACID | - |
dc.subject.keywordPlus | RECOGNITION | - |
dc.subject.keywordPlus | HCLO | - |
dc.subject.keywordPlus | HOCL | - |
dc.subject.keywordPlus | HYDRAZIDE | - |
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Tel : 052-217-1404 / Email : scholarworks@unist.ac.kr
Copyright (c) 2023 by UNIST LIBRARY. All rights reserved.
ScholarWorks@UNIST was established as an OAK Project for the National Library of Korea.