There are no files associated with this item.
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.startPage | 851 | - |
dc.citation.title | NATURE COMMUNICATIONS | - |
dc.citation.volume | 10 | - |
dc.contributor.author | Song, Choong Eui | - |
dc.contributor.author | Park, Si Joon | - |
dc.contributor.author | Hwang, In-Soo | - |
dc.contributor.author | Jung, Min Jung | - |
dc.contributor.author | Shim, So Young | - |
dc.contributor.author | Bae, Han Yong | - |
dc.contributor.author | Jung, Ji Yoon | - |
dc.date.accessioned | 2023-12-21T19:37:55Z | - |
dc.date.available | 2023-12-21T19:37:55Z | - |
dc.date.created | 2019-02-22 | - |
dc.date.issued | 2019-02 | - |
dc.description.abstract | The manipulation of the transition states of a chemical process is essential to achieve the desired selectivity. In particular, transition states of chemical reactions can be significantly modified in a confined environment. We report a catalytic reaction with remarkable amplification of stereochemical information in a confined water cage. Surprisingly, this amplification is significantly dependent on droplet size. This water-induced chirality amplification stems from the hydrophobic hydration effects, which ensures high proximity of the catalyst and substrates presumably at the transition state, leading to higher enantioselectivity. Flow and batch reactors were evaluated to confirm the generality of this water-induced chirality amplification. Our observation on efficient chiral induction in confined water cages might lead to an understanding of the chirality amplification in the prebiotic era, which is a key feature for the chemical evolution of homochirality. | - |
dc.identifier.bibliographicCitation | NATURE COMMUNICATIONS, v.10, pp.851 | - |
dc.identifier.doi | 10.1038/s41467-019-08792-z | - |
dc.identifier.issn | 2041-1723 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/26225 | - |
dc.identifier.url | https://www.nature.com/articles/s41467-019-08792-z | - |
dc.language | 영어 | - |
dc.publisher | Nature Publishing Group | - |
dc.title | Hydrophobic chirality amplification in confined water cages | - |
dc.type | Article | - |
dc.description.isOpenAccess | TRUE | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Tel : 052-217-1404 / Email : scholarworks@unist.ac.kr
Copyright (c) 2023 by UNIST LIBRARY. All rights reserved.
ScholarWorks@UNIST was established as an OAK Project for the National Library of Korea.