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DC Field | Value | Language |
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dc.citation.endPage | 13772 | - |
dc.citation.number | 52 | - |
dc.citation.startPage | 13767 | - |
dc.citation.title | CHEMISTRY-A EUROPEAN JOURNAL | - |
dc.citation.volume | 24 | - |
dc.contributor.author | Bae, Han Yong | - |
dc.contributor.author | List, Benjamin | - |
dc.date.accessioned | 2023-12-21T20:12:05Z | - |
dc.date.available | 2023-12-21T20:12:05Z | - |
dc.date.created | 2019-02-11 | - |
dc.date.issued | 2018-09 | - |
dc.description.abstract | The Mukaiyama aldol reaction is a widely applied carbon-carbon bond forming reaction. However, despite numerous well-established methods using aldehydes as acceptors, only few examples exist with ketones. Here we report a highly practical catalytic approach to this transformation, namely, the triflimide catalyzed Mukaiyama aldol reaction of silyl ketene acetals with ketones. This method exhibits a broad substrate scope, is very rapid, tolerates functionalized substrates, and requires only parts-per-million catalyst loadings with preparative scale reactions up to hundreds of grams in excellent purity (>99%). | - |
dc.identifier.bibliographicCitation | CHEMISTRY-A EUROPEAN JOURNAL, v.24, no.52, pp.13767 - 13772 | - |
dc.identifier.doi | 10.1002/chem.201803142 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.scopusid | 2-s2.0-85052922780 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/25866 | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201803142 | - |
dc.identifier.wosid | 000445447300013 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Triflimide: An Overlooked High-Performance Catalyst of the Mukaiyama Aldol Reaction of Silyl Ketene Acetals with Ketones | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | aldol reaction | - |
dc.subject.keywordAuthor | Lewis acids | - |
dc.subject.keywordAuthor | Mukaiyama aldol reaction | - |
dc.subject.keywordAuthor | parts-per-million | - |
dc.subject.keywordAuthor | silyl ketene acetal | - |
dc.subject.keywordAuthor | tertiary aldols | - |
dc.subject.keywordPlus | LEWIS-ACID CATALYST | - |
dc.subject.keywordPlus | ONE-POT | - |
dc.subject.keywordPlus | ENANTIOSELECTIVE SYNTHESIS | - |
dc.subject.keywordPlus | SEQUENTIAL REACTIONS | - |
dc.subject.keywordPlus | CARBONYL-COMPOUNDS | - |
dc.subject.keywordPlus | CASCADE REACTION | - |
dc.subject.keywordPlus | CRUCIAL ROLE | - |
dc.subject.keywordPlus | ADDITIONS | - |
dc.subject.keywordPlus | BASE | - |
dc.subject.keywordPlus | ORGANOCATALYSIS | - |
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