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DC Field | Value | Language |
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dc.citation.number | 29 | - |
dc.citation.startPage | 1801478 | - |
dc.citation.title | ADVANCED ENERGY MATERIALS | - |
dc.citation.volume | 8 | - |
dc.contributor.author | Qin, Qing | - |
dc.contributor.author | Jang, Haeseong | - |
dc.contributor.author | Chen, Lulu | - |
dc.contributor.author | Nam, Gyutae | - |
dc.contributor.author | Liu, Xien | - |
dc.contributor.author | Cho, Jaephil | - |
dc.date.accessioned | 2023-12-21T20:09:08Z | - |
dc.date.available | 2023-12-21T20:09:08Z | - |
dc.date.created | 2018-11-06 | - |
dc.date.issued | 2018-10 | - |
dc.description.abstract | Reducing the consumption of noble metals in energy devices, such as fuel cells, zinc-air batteries, and water splitting cells, is a core issue for achieving an environmentally sustainable society. Herein, two highly efficient electrocatalysts are synthesized, composed of N, P codoped carbon (NPC) modified with noble metals phosphides (RhxP/NPC and RuP/NPC) through pyrolysis of a mixture of RhCl(3)xH(2)O or RuCl3 xH(2)O, respectively, with phytic acid. Unlike the reported rhodium and ruthenium phosphides, RhxP/NPC and RuP/NPC have a low loading of Rh (approximate to 0.4 wt%) and Ru (approximate to 0.5 wt%) and yet still exhibit excellent trifunctional activities for oxygen reduction, oxygen evolution, and hydrogen evolution reactions. For hydrogen evolution, RhxP/NPC shows a Pt-like activity and excellent durability in acidic medium. Notably, RuP/NPC becomes more active after 2000 cycles in the durability test. For oxygen reduction, both of the catalysts show a half-wave potential of 0.89 V, which is positively shifted 40 mV relative to that of Pt/C (0.85 V) in 0.1 m KOH. In addition, RhxP/NPC and RuP/NPC also exhibit activities superior to that of IrO2 in oxygen evolution. Finally, zinc-air batteries and water splitting cells assembled with RhxP/NPC and RuP/NPC catalysts display good performance. | - |
dc.identifier.bibliographicCitation | ADVANCED ENERGY MATERIALS, v.8, no.29, pp.1801478 | - |
dc.identifier.doi | 10.1002/aenm.201801478 | - |
dc.identifier.issn | 1614-6832 | - |
dc.identifier.scopusid | 2-s2.0-85052647281 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/25145 | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/abs/10.1002/aenm.201801478 | - |
dc.identifier.wosid | 000447257000005 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Low Loading of RhxP and RuP on N, P Codoped Carbon as Two Trifunctional Electrocatalysts for the Oxygen and Hydrogen Electrode Reactions | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical; Energy & Fuels; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter | - |
dc.relation.journalResearchArea | Chemistry; Energy & Fuels; Materials Science; Physics | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | hydrogen evolution reaction | - |
dc.subject.keywordAuthor | oxygen evolution reaction | - |
dc.subject.keywordAuthor | oxygen reduction reaction | - |
dc.subject.keywordAuthor | water splitting cell | - |
dc.subject.keywordAuthor | zinc-air batteries | - |
dc.subject.keywordPlus | NANOSTRUCTURED NICKEL PHOSPHIDE | - |
dc.subject.keywordPlus | METAL-FREE ELECTROCATALYSTS | - |
dc.subject.keywordPlus | ZINC-AIR BATTERIES | - |
dc.subject.keywordPlus | EVOLUTION REACTION | - |
dc.subject.keywordPlus | REDUCTION REACTION | - |
dc.subject.keywordPlus | BIFUNCTIONAL ELECTROCATALYST | - |
dc.subject.keywordPlus | WATER OXIDATION | - |
dc.subject.keywordPlus | DOPED CARBON | - |
dc.subject.keywordPlus | FREE CATALYSTS | - |
dc.subject.keywordPlus | EFFICIENT | - |
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