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DC Field | Value | Language |
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dc.citation.endPage | 2686 | - |
dc.citation.number | 9 | - |
dc.citation.startPage | 2679 | - |
dc.citation.title | ACS APPLIED MATERIALS & INTERFACES | - |
dc.citation.volume | 2 | - |
dc.contributor.author | Chen, John Jun-An | - |
dc.contributor.author | Chen, Teresa L. | - |
dc.contributor.author | Kim, BongSoo | - |
dc.contributor.author | Poulsen, Daniel A. | - |
dc.contributor.author | Mynar, Justin L. | - |
dc.contributor.author | Frechet, Jean M. J. | - |
dc.contributor.author | Ma, Biwu | - |
dc.date.accessioned | 2023-12-22T06:44:00Z | - |
dc.date.available | 2023-12-22T06:44:00Z | - |
dc.date.created | 2018-09-10 | - |
dc.date.issued | 2010-09 | - |
dc.description.abstract | New soluble quinacridone-based molecules have been developed as electron donor materials for solution-processed organic solar cells. By functionalizing the pristine pigment core of quinacridone with solubilizing alkyl chains and light absorbing/charge transporting thiophene units, i.e., bithiophene (BT) and thienylbenzo[c][1,2,5]thiadiazolethienyl (BTD), we prepared a series of multifunctional quinacridone-based molecules. These molecular donors show intense absorption in the visible spectral region, and the absorption range and intensity are well-tuned by the interaction between the quinacridone core and the incorporated thiophene units. The thin film absorption edge extends with the expansion of molecular conjugation, i.e., 552 nm for N,N'-di(2-ethylhexyl)quinacridone (QA), 592 nm for 2,9-Bis(5'-hexy1-2,2'-bithiophene)-N,N'-di(2-ethylhexyl)quinacridone (QA-BT), and 637 nm for 4-(5hexylthiophen-2-y1)-7-(thiophen-2-Abenzo[c][1,2,5]chiadiazole (QA-BTD). The change of molecular structure also influences the electrochemical properties. Observed from cyclic voltammetry measurements, the oxidation and reduction potentials (vs ferrocene) are 0.7 and 1.83 V for QA, 0.54 and 1.76 V for QA-BT, and 0.45 and 1.68 V for QA-BTD. Uniform thin films can be generated from both single component molecular solutions and blend solutions of these molecules with [6,61-phenyl C70-butyric acid methyl ester (PC70BM). The blend films exhibit space-charge limited current (SCLC) hole mobilities on the order of 1 x 10(-4) cm(2) V-1 s(-1) Bulk heterojunction (BHJ) solar cells using these soluble molecules as donors and PC70BM as the acceptor were fabricated. Power conversion efficiencies (PCEs) of up to 2.22% under AM 1.5 G simulated 1 sun solar illumination have been achieved and external quantum efficiencies (EQEs) reach as high as similar to 45%. | - |
dc.identifier.bibliographicCitation | ACS APPLIED MATERIALS & INTERFACES, v.2, no.9, pp.2679 - 2686 | - |
dc.identifier.doi | 10.1021/am100523g | - |
dc.identifier.issn | 1944-8244 | - |
dc.identifier.scopusid | 2-s2.0-79151482336 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/24821 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/am100523g | - |
dc.identifier.wosid | 000282017700030 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Quinacridone-Based Molecular Donors for Solution Processed Bulk-Heterojunction Organic Solar Cells | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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