There are no files associated with this item.
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 12319 | - |
dc.citation.number | 17 | - |
dc.citation.startPage | 12310 | - |
dc.citation.title | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | - |
dc.citation.volume | 42 | - |
dc.contributor.author | Han, Jae-Yun | - |
dc.contributor.author | Kim, Chang-Hyun | - |
dc.contributor.author | Lim, Hankwon | - |
dc.contributor.author | Lee, Kwan-Young | - |
dc.contributor.author | Ryi, Shin-Kun | - |
dc.date.accessioned | 2023-12-21T22:18:15Z | - |
dc.date.available | 2023-12-21T22:18:15Z | - |
dc.date.created | 2018-07-31 | - |
dc.date.issued | 2017-04 | - |
dc.description.abstract | In this study, we present an intermetallic diffusion barrier coating using a newly developed blowing coating method for a thermally stable Pd-based composite membrane on porous stainless steel (PSS). A tubular PSS sample with 1/2 inch (12.7 mm) in diameter and 450 mm in length was used for the support. The support was welded with a stainless-steel cap and a 450-mm-long stainless-steel tube for each end. Before the diffusion barrier coating, the large-sized entrance pores were gradually blocked with sub-micron (similar to 500 nm) and nano (50 80 nm) yttria stabilized zirconia (YSZ). 8YSZ, i.e., 8wt.% YSZ, was used for the interdiffusion barrier material and dispersed on the surface of the pre-treated PSS using the blowing coating method. The blowing coating method has 4 steps: (i) spraying the 17 wt. % 8YSZ paste on the surface of the PSS tube,(ii) blowing the paste using compressed air,(iii) drying at room temperature, and (iv) heat treatment at 923 K for 2 h in air. Steps (i) and (ii) were repeated 3 times to have a similar to 240 nm thick 8YSZ layer. A thin palladium layer (similar to 3 mu m) was deposited on the pre-treated PSS using electroless plating, and the membrane stability was tested at 673-773 K for similar to 200 h. A hydrogen permeation flux of 9.86 x 10(-2) mol m(-2) s(-1) and an H-2/N-2 selectivity of 595 were obtained at 773 K and a transmembrane pressure difference of 20 kPa. The surface and cross-sectional SEM/EDX analysis confirmed that the 8YSZ layer sufficiently prevented the interdiffusion between Pd and PSS elements, such as Fe, Cr and Ni. | - |
dc.identifier.bibliographicCitation | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, v.42, no.17, pp.12310 - 12319 | - |
dc.identifier.doi | 10.1016/j.ijhydene.2017.03.053 | - |
dc.identifier.issn | 0360-3199 | - |
dc.identifier.scopusid | 2-s2.0-85016724770 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/24489 | - |
dc.identifier.url | https://www.sciencedirect.com/science/article/pii/S0360319917309722?via%3Dihub | - |
dc.identifier.wosid | 000403381500026 | - |
dc.language | 영어 | - |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
dc.title | Diffusion barrier coating using a newly developed blowing coating method for a thermally stable Pd membrane deposited on porous stainless-steel support | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Tel : 052-217-1404 / Email : scholarworks@unist.ac.kr
Copyright (c) 2023 by UNIST LIBRARY. All rights reserved.
ScholarWorks@UNIST was established as an OAK Project for the National Library of Korea.