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DC Field | Value | Language |
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dc.citation.endPage | 8442 | - |
dc.citation.number | 28 | - |
dc.citation.startPage | 8438 | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 57 | - |
dc.contributor.author | Yu, Soo-Young | - |
dc.contributor.author | Mahmood, Javeed | - |
dc.contributor.author | Noh, Hyuk-Jun | - |
dc.contributor.author | Seo, Jeong-Min | - |
dc.contributor.author | Jung, Sun-Min | - |
dc.contributor.author | Shin, Sun-Hee | - |
dc.contributor.author | Im, Yoon-Kwang | - |
dc.contributor.author | Jeon, In-Yup | - |
dc.contributor.author | Baek, Jong-Beom | - |
dc.date.accessioned | 2023-12-21T20:37:41Z | - |
dc.date.available | 2023-12-21T20:37:41Z | - |
dc.date.created | 2018-07-27 | - |
dc.date.issued | 2018-07 | - |
dc.description.abstract | There have been extensive efforts to synthesize crystalline covalent triazine-based frameworks (CTFs) for practical applications and to realize their potential. The phosphorus pentoxide (P2O5)-catalyzed direct condensation of aromatic amide instead of aromatic nitrile to form triazine rings. P2O5-catalyzed condensation was applied on terephthalamide to construct a covalent triazine-based framework (pCTF-1). This approach yielded highly crystalline pCTF-1 with high specific surface area (2034.1m(2)g(-1)). At low pressure, the pCTF-1 showed high CO2 (21.9wt% at 273K) and H-2 (1.75wt% at 77K) uptake capacities. The direct formation of a triazine-based COF was also confirmed by model reactions, with the P2O5-catalyzed condensation reaction of both benzamide and benzonitrile to form 1,3,5-triphenyl-2,4,6-triazine in high yield. | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.57, no.28, pp.8438 - 8442 | - |
dc.identifier.doi | 10.1002/anie.201801128 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.scopusid | 2-s2.0-85049586459 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/24456 | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201801128 | - |
dc.identifier.wosid | 000437668700010 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Direct Synthesis of a Covalent Triazine-Based Framework from Aromatic Amides | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | covalent triazine frameworks | - |
dc.subject.keywordAuthor | crystalline organic networks | - |
dc.subject.keywordAuthor | cyclotrimerization | - |
dc.subject.keywordAuthor | microporous materials | - |
dc.subject.keywordAuthor | phosphorus pentoxide | - |
dc.subject.keywordPlus | POROUS ORGANIC POLYMERS | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordPlus | CO2 | - |
dc.subject.keywordPlus | CAPTURE | - |
dc.subject.keywordPlus | CRYSTALLINE | - |
dc.subject.keywordPlus | CATALYSIS | - |
dc.subject.keywordPlus | SEPARATION | - |
dc.subject.keywordPlus | PLATFORM | - |
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